An Improved Synthesis of Fluorinated Imidoylsilanes

Chie Akamatsu; Atsushi Yamauchi; Takeshi Kobayashi; Yu Ozeki; Jun Takagi; Hideki Amii; Kenji Uneyama

doi:10.1055/s-2006-942361

PAPER

An Improved Synthesis of Fluorinated Imidoylsilanes

Chie Akamatsu, Atsushi Yamauchi, Takeshi Kobayashi, Yu Ozeki, Jun Takagi, Hideki Amii*, Kenji Uneyama*
Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushimanaka 3-1-1, Okayama 700-8530, Japan
Fax: +81(86)2518021; e-Mail: uneyamak@cc.okayama-u.ac.jp;

Abstract

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Abstract

A practical and efficient method for the preparation of fluorinated imidoylsilanes is described. The key step involves finely controlled activation of C-Cl and C-Br bonds in fluorinated imidoyl chlorides and bromides, respectively.

Key words

magnesium - fluorine - imines - umpolung - imidoylsilane

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References

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