Samarium(III) Triflate Catalyzed Conjugate Addition of Amines to Electron-Deficient Alkenes

J. S. Yadav; A. Ramesh Reddy; Y. Gopal Rao; A. V. Narsaiah; B. V. S. Reddy

doi:10.1055/s-2007-990876

SHORTPAPER

Samarium(III) Triflate Catalyzed Conjugate Addition of Amines to Electron-Deficient Alkenes [1]

J. S. Yadav*, A. Ramesh Reddy, Y. Gopal Rao, A. V. Narsaiah, B. V. S. Reddy
Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Fax: +91(40)27160512;

Abstract

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Abstract

Amines undergo smooth nucleophilic addition to α,β-unsaturated compounds in the presence of a catalytic amount of samarium(III) triflate at ambient temperature to produce the corresponding β-amino compounds in excellent yields. This method is simple, convenient, and works efficiently under mild conditions.

Key words

amines - α,β-unsaturated compounds - conjugate addition - β-amino derivatives

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References

References and Notes

IICT Communication No. 060901.

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