H2O2/Tf2O System: An Efficient Oxidizing Reagent for Selective Oxidation of Sulfanes

Mohammad Mehdi Khodaei; Kiumars Bahrami; Ahmad Karimi

doi:10.1055/s-2008-1067019

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Synthesis 2008(11): 1682-1684
DOI: 10.1055/s-2008-1067019

SHORTPAPER

H₂O₂/Tf₂O System: An Efficient Oxidizing Reagent for Selective Oxidation of Sulfanes

Mohammad Mehdi Khodaei*^a,b, Kiumars Bahrami*^a,b, Ahmad Karimi^a,b
^a Department of Chemistry, Razi University, Kermanshah 67149, Iran
^b Nanoscience and Nanotechnology Research Center (NNRC), Razi University, Kermanshah 67149, Iran
Fax: +98(831)4274559; e-Mail: mmkhoda@razi.ac.ir; e-Mail: Kbahrami2@hotmail.com;

Further Information

Publication History

Received 9 January 2008
Publication Date:
11 April 2008 (online)

Abstract
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Abstract

A versatile procedure for the oxidation of sulfanes to sulfoxides without any overoxidation to sulfones has been reported. It is noteworthy that the reaction tolerates oxidatively sensitive functional groups and that the sulfur atom is selectively oxidized.

Key words

sulfoxides - chemoselectivity - environmentally friendly - triflic anhydride

References

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