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Special Issue Dedicated to Professor Shinji Murai – Part II
Special Issue Dedicated to Professor Shinji Murai – Part I
Functional Organic Molecules
Recent Advances in Metal-Catalyzed Ring Construction
Synthesis in Industry
Recent Advances in Amide Bond Formation
Domino C–H Functionalization/Cascade Catalysis
Bürgenstock Special Section 2019
Halogenation Methods (with a View Towards Radioimaging Applications)
Bürgenstock Special Section 2018
Amination Reactions in Organic Synthesis
Ruthenium in Organic Synthesis
Golden Anniversary Issue – 50 Years Synthesis – Part II
Golden Anniversary Issue – 50 Years Synthesis – Part I
Aryne Chemistry in Synthesis
Cycloadditions – Established and Novel Trends – in Celebration of the 70th Anniversary of the Nobel Prize Awarded to Otto Diels and Kurt Alder
Asymmetric C–H Functionalization
Special Issue dedicated to Prof. Alain Krief
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Virtual Golden Anniversary Issue – 50 Years Synthesis
Editor's choice
Virtual India Collection: Most Cited SYNTHESIS Articles and Related Synthetic Methodology Reviews from Science of Synthesis
Bond Activation – in Honor of Prof. Shinji Murai
20 most-cited SYNTHESIS articles published in 2019/2020
Virtual Special Issue dedicated to Prof. Sarah Reisman, recipient of the 2019 Dr. Margaret Faul Women in Chemistry Award
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Issue eFirst
Korneev, Sergei M.:
Hydrocinnamic Acids: Application and Strategy of Synthesis
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PDF (358 kb)
Wu, Hua; He, Yu-Ping; Shi, Feng:
Recent Advances in Chiral Phosphoric Acid Catalyzed Asymmetric Reactions for the Synthesis of Enantiopure Indole Derivatives
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PDF (1288 kb)
Chatalova-Sazepin, Claire; Hemelaere, Rémy; Paquin, Jean-François; Sammis, Glenn M.:
Recent Advances in Radical Fluorination
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PDF (513 kb)
Sani, Monica; Zanda, Matteo:
Recent Advances in the Synthesis and Medicinal Chemistry of SF
5
and SF
4
Cl Compounds
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PDF (697 kb)
Nori, Valeria; Sinibaldi, Arianna; Pesciaioli, Fabio; Carlone, Armando:
Impact of Design of Experiments in the Optimisation of Catalytic Reactions in Academia
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PDF (1897 kb)
Wan, Dan-Hong; Yang, Hai-Bin:
Research Progress on
N
-Heterocyclic Carbene Catalyzed Reactions for Synthesizing Ketones through Radical Mechanism
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PDF (465 kb)
Brandão, Pedro; Pineiro, Marta; Burke, Anthony J.:
Tryptanthrin and Its Derivatives in Drug Discovery: Synthetic Insights
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Goebel, Jonas F.; Zeng, Zhongyi; Gooßen, Lukas J.:
Biaryl Synthesis via Electrooxidative Transition-Metal-Catalyzed C–H Activation
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PDF (389 kb)
Didier, Dorian:
Forging C–C Bonds through Intramolecular Oxidative Coupling of Organoborates – An Overview
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PDF (490 kb)
Pellissier, Hélène:
The Use of Domino Reactions for the Synthesis of Chiral Rings
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PDF (516 kb)
Oh, Eun Hye; Kim, Hyun Jin; Han, Soo Bong:
Recent Developments in Visible-Light-Catalyzed Multicomponent Trifluoromethylation of Unsaturated Carbon–Carbon Bonds
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PDF (543 kb)
Kindt, Stephanie; Heinrich, Markus R.:
Recent Advances in Meerwein Arylation Chemistry
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PDF (928 kb)
Federsel, Hans-Jürgen:
Taking the Green Road Towards Pharmaceutical Manufacturing
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PDF (1046 kb)
Zhao, Baoli; Liu, Yunyun:
Step-Economical C–H Activation Reactions Directed by In Situ Amidation
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PDF (409 kb)
Zhu, Haoran; Driver, Tom G.:
Recent Advances to Mediate Reductive Processes of Nitroarenes Using Single-Electron Transfer, Organomagnesium, or Organozinc Reagents
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PDF (778 kb)
Praveen, P. J.; Parameswaran, P. S.; Majik, M. S.:
Bis(indolyl)methane Alkaloids: Isolation, Bioactivity, and Syntheses
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Nithiy, Nisha; Rosa, David; Orellana, Arturo:
Carbon–Carbon Bond Formation through Palladium Homoenolates
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PDF (317 kb)
Giustiniano, Mariateresa; Novellino, Ettore; Tron, Gian Cesare:
Nitrile
N
-Oxides and Nitrile Imines as
New Fuels
for the Discovery of Novel Isocyanide-Based Multicomponent Reactions
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Zhong, Sishi; Xu, Lei; Cai, Yunfei:
Recent Advances on Piancatelli Reactions and Related Cascade Processes
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Hoque, Md Emdadul; Hassan, Mirja Md Mahamudul; Haldar, Chabush; Dey, Sayan; Guria, Saikat; Chaturvedi, Jagriti; Chattopadhyay, Buddhadeb:
Catalyst Engineering through Heterobidentate (N–X-Type) Ligand Design for Iridium-Catalyzed Borylation
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Hirano, Koji:
Catalytic Asymmetric Construction of CF
3
-Substituted Chiral sp
3
Carbon Centers
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Roselló, María Sánchez; del Pozo, Carlos; Fustero, Santos:
A Decade of Advance in the Asymmetric Vinylogous Mannich Reaction
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Nielsen, Mogens Brøndsted:
Sonogashira-Like Coupling Reactions with Phosphine–Gold(I) Alkynyl Complexes
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PDF (944 kb)
Shintani, Ryo:
Rhodium-Catalyzed Stitching Reactions for the Facile Synthesis of Extended π-Conjugated Compounds
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PDF (912 kb)
Wang, Yongtao; Yao, Jia; Li, Haoran:
Aerobic Oxidations via Organocatalysis: A Mechanistic Perspective
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Echeverria, Pierre-Georges; Ayad, Tahar; Phansavath, Phannarath; Ratovelomanana-Vidal, Virginie:
Recent Developments in Asymmetric Hydrogenation and Transfer Hydrogenation of Ketones and Imines through Dynamic Kinetic Resolution
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Heinrich, Clément F.; Peter, Clovis; Miesch, Laurence; Geoffroy, Philippe; Miesch, Michel:
Diastereo- and Enantioselective Synthesis of Polyfunctionalized Diquinanes, Hydrindanes, and Decalins Bearing a Hydroxyl Group at the Ring Junction
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PDF (506 kb)
Zhao, Hongyi; Pan, Huanhuan; Yao, Yi; Huang, Jian; Chen, Yang:
Recent Advances in the Total Synthesis of Cephalotane-Type Norditerpenoids from
Cephalotaxus sinensis
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PDF (587 kb)
Yang, Yun; Jones, Christopher R.:
The Aryne Ene Reaction
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PDF (561 kb)
Lee, Kyu Ree; Lee, Yu Lim; Choi, Kyu In; Lee, Sang-gi:
Cooperative Rh(II)/Pd(0) Dual Catalysis for the Synthesis of Carbo- and Heterocyclic Compounds
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PDF (490 kb)
Chakraborty, Indrajit; Jana, Samaresh:
Synthetic Developments on the Indolizidine Alkaloid, Harmicine
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PDF (278 kb)
Singh, Fateh V.; Wirth, Thomas:
Oxidative Rearrangements with Hypervalent Iodine Reagents
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PDF (328 kb)
Yoshida, Hiroto:
Stannylation Reactions under Base Metal Catalysis: Some Recent Advances
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PDF (515 kb)
Amat, Mercedes; Llor, Núria; Guignard, Guillaume; Bosch, Joan:
Synthesis of Fluvirucins and Their Aglycons, the Fluvirucinins
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PDF (974 kb)
Ferreira de Paiva, Walysson; de Freitas Rego, Yuri; de Fátima, Ângelo; Fernandes, Sergio Antonio:
The Povarov Reaction: A Versatile Method to Synthesize Tetrahydroquinolines, Quinolines and Julolidines
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PDF (666 kb)
Chen, Wenzhang; Vincent, Stéphane P.:
Copillar[5]arene Chemistry: Synthesis and Applications
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PDF (1495 kb)
Shin, Inji; Lim, Hee Nam; Hong, Wan Pyo:
1,4-Azaborines: Origin, Modern Synthesis, and Applications as Optoelectronic Materials
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PDF (791 kb)
Fernandes, Rodney A.; Mulay, Sandip V.:
Chiral Cups (Calixarenes) via Dötz Benzannulation
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PDF (328 kb)
Su, Yong-Liang; Doyle, Michael P.:
Application of α-Aminoalkyl Radicals as Reaction Activators
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PDF (711 kb)
Saeidian, Hamid; Abdoli, Morteza; Mirjafary, Zohreh:
Synthesis of Acyclic and Cyclic Sulfamates: A Review
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PDF (1183 kb)
Zhou, Wen-Jun; Zhang, Yi-Han; Gui, Yong-Yuan; Sun, Liang; Yu, Da-Gang:
Merging Transition-Metal Catalysis with Photoredox Catalysis: An Environmentally Friendly Strategy for C–H Functionalization
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PDF (682 kb)
Champagne, Pier Alexandre; Desroches, Justine; Paquin, Jean-François:
Organic Fluorine as a Hydrogen-Bond Acceptor: Recent Examples and Applications
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PDF (1235 kb)
Issue Accepted Manuscripts
Reyes, Efraim; Prieto, Liher; Carrillo, Luisa; Uria, Uxue; Vicario, Jose:
Recent Developments in Transannular Reactions
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Cheng, Li; Lin, Quan; Chen, Yunrong; Gong, Hegui:
Recent Progress on Transition-Metal-Mediated Reductive C(sp3)‒O Bond Radical addition and Coupling Reactions
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PDF (3959 kb)
Schindler, Corinna S; Chamness, Stephen A; Traficante, Emily F; Vogel, Trenton R:
Synthetic Strategies Towards the Meroterpenoids Cochlearols A and B from Ganoderma Cochlear
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PDF (2835 kb)
Schindler, Corinna S; Cala, Lara; Gaviria, Mario A; Kim, Scott L; Vogel, Trenton R:
Recognition of Symmetry as a Powerful Tool in Natural Product Synthesis
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PDF (2626 kb)
Rombach, David; Wagenknecht, Hans-Achim:
Photochemical activation of sulfur hexafluoride – a tool for fluorination and pentafluorosulfanylation reactions
PDF (1513 kb)
Issue 13/2022
Borys, Andryj M.; Hevia, Eva:
Mechanisms of the Nickel-Catalysed Hydrogenolysis and Cross-Coupling of Aryl Ethers
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PDF (748 kb)
Depa, Wojciech; Bisek, Bartosz; Górecki, Marcin; Michalak, Michał:
Epoxydibenzo[
b
,
f
][1,5]diazocines: From a Hidden Structural Motif to an Efficient Solvent-Free Synthetic Protocol
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PDF (1063 kb)
Issue 12/2022
Wang, Wanshu; Gao, Lu; Song, Zhenlei:
Synthetic Approaches for the Construction of Five- and Six-Membered Silaazacycles
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PDF (677 kb)
Nishimoto, Yoshihiro; Sugihara, Naoki; Yasuda, Makoto:
C(sp
3
)–F Bond Transformation of Perfluoroalkyl Compounds Mediated by Visible-Light Photocatalysis: Spin-Center Shifts and Radical/Polar Crossover Processes via Anionic Intermediates
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PDF (648 kb)
Beller, Marc Paul; Koert, Ulrich:
Synthetic Studies on Chromone Natural Products: The Preussochromones
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PDF (367 kb)
Issue 11/2022
Hassan, Diandra Safira; Kariapper, F. Safia; Lynch, Ciarán C.; Wolf, Christian:
Accelerated Asymmetric Reaction Screening with Optical Assays
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Kawamoto, Takuji; Kamimura, Akio:
Recent Advances in Radical Reactions of Vinyl Triflates and Their Derivatives
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PDF (470 kb)
Zheng, Yue; Tian, Lifang; Ramadoss, Velayudham; Zhang, Hui; Zhu, Li-Li; Wang, Yahui:
Recent Developments in N
2
-Selective Functionalizations of 1,2,3-Triazoles
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PDF (591 kb)
Liu, Ying-Ying; Sun, Shao-Han; Min, Xiang-Ting; Wan, Boshun; Chen, Qing-An:
Transition-Metal-Catalyzed Decarbonylative Functionalization of Phthalimides
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PDF (577 kb)
Issue 10/2022
Shiozuka, Akira; Sekine, Kohei; Kuninobu, Yoichiro:
Photoinduced Organic Reactions by Employing Pyrene Catalysts
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PDF (576 kb)
Tsuchiya, Naoki; Sheppard, Tom D.; Nishikata, Takashi:
Tertiary Alkylative Suzuki–Miyaura Couplings
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PDF (603 kb)
Issue 09/2022
Sun, Xin; Li, Bi-Jie:
Acyclic Quaternary Carbon Stereocenters through Transition-Metal-Catalyzed Enantioselective Functionalization of Unsaturated Hydrocarbons
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PDF (784 kb)
Sweet, Jamie S.; Knipe, Peter C.:
Catalytic Enantioselective Synthesis of C–N Atropisomeric Heterobiaryls
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PDF (697 kb)
Ye, Zhi-Shi; Li, Jin-Chen; Wang, Gang:
Transition-Metal-Catalyzed Enantioselective Synthesis of Indoles from 2-Alkynylanilines
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PDF (553 kb)
Issue 08/2022
Whalley, David M.; Greaney, Michael F.:
Recent Advances in the Smiles Rearrangement: New Opportunities for Arylation
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PDF (483 kb)
Liu, Ting; Liu, Jian; He, Jin; Hong, Yu; Zhou, Han; Liu, Yin-Ling; Tang, Shi:
Recent Advances in Photoinduced Perfluoroalkylation Using Perfluoroalkyl Halides as the Radical Precursors
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PDF (943 kb)
Yuan, Wei; He, Chuan:
Enantioselective C–H Functionalization toward Silicon-Stereogenic Silanes
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PDF (555 kb)
Diesendorf, Nina; Heinrich, Markus R.:
Current Advances in Meerwein-type Radical Alkene Functionalizations
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PDF (798 kb)
Yan, Biwei; Guo, Wusheng:
Recent Advances in Decarboxylative Conversions of Cyclic Carbonates and Beyond
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PDF (797 kb)
Issue 07/2022
Katayama, Yuri; Mitsunuma, Harunobu; Kanai, Motomu:
Recent Progress in Chromium-Mediated Carbonyl Addition Reactions
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PDF (638 kb)
Andrews, Jonathan A.; Willis, Michael C.:
DABSO – A Reagent to Revolutionize Organosulfur Chemistry
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PDF (536 kb)
Qin, Xu-Long; Xu, Li-Jun; Han, Fu-She:
Recent Advances in Organocatalyzed Asymmetric Reduction of Prochiral Ketones: An Update
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PDF (456 kb)
Ding, Bo; Xue, Qilin; Jia, Shihu; Cheng, Hong-Gang; Zhou, Qianghui:
Recent Advances in Catalytic Nonenzymatic Kinetic Resolution of Tertiary Alcohols
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PDF (643 kb)
Issue 06/2022
Tian, Ze-Yu; Ma, Yu; Zhang, Cheng-Pan:
Alkylation Reactions with Alkylsulfonium Salts
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PDF (741 kb)
Ahsanullah, Ahsanullah; Hassan, Abbas; Ansari, Farzana L.; Rademann, Jörg:
Integration of
C
-Acylation in the Solid-Phase Synthesis of Peptides and Peptidomimetics Employing Meldrum’s Acid, Phosphorus, and Sulfur Ylides
Full Text
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PDF (818 kb)
Hamdane, Yousra; Poupart, Julien; Lubell, William D.:
N
-Amino-imidazol-2-one (Nai) Residues as Tools for Peptide Mimicry: Synthesis, Conformational Analysis and Biomedical Applications
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PDF (1291 kb)
Yang, Zhao-Ying; Zhang, Ming; Wang, Xiao-Chen:
Synthesis and Applications of Chiral Bicyclic Bisborane Catalysts
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PDF (467 kb)
Paris, Timothy J.; Willand-Charnley, Rachel:
Modern Synthesis and Chemistry of Stabilized Ketene
N
,
O
-Acetals
Full Text
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PDF (1804 kb)
Xu, Houchao; Dickschat, Jeroen S.:
Mechanistic Investigations on Microbial Type I Terpene Synthases through Site-Directed Mutagenesis
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PDF (2850 kb)
Issue 05/2022
Ma, Xiao-Yan; Shao, Fu-Qiang; Hu, Xinjun; Liu, Xingyong:
Progress in the Synthesis of
N
-Acyl-
N
,
O
-acetals
Full Text
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PDF (615 kb)
Miller, Eric R.; Scheidt, Karl A.:
Enantioselective Syntheses of Yohimbine Alkaloids: Proving Grounds for New Catalytic Transformations
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PDF (348 kb)
Lu, Zheng; Shang, Mingzhou; Lu, Hongjian:
Organic Sulfinic Acids and Salts in Visible Light-Induced Reactions
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PDF (610 kb)
Lamberth, Clemens:
Organic Isocyanates and Isothiocyanates: Versatile Intermediates in Agrochemistry
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PDF (399 kb)
Winterson, Bethan; Patra, Tuhin; Wirth, Thomas:
Hypervalent Bromine(III) Compounds: Synthesis, Applications, Prospects
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PDF (847 kb)
Issue 02/2022
Wei, Baosheng; Knochel, Paul:
Recent Advances in Cross-Couplings of Functionalized Organozinc Reagents
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PDF (623 kb)
Oroz, Paula; Avenoza, Alberto; Busto, Jesús H.; Corzana, Francisco; Zurbano, María M.; Peregrina, Jesús M.:
Strategies for the Synthesis of Selenocysteine Derivatives
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PDF (769 kb)
Glueck, David S.:
Asymmetric Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs)
Full Text
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PDF (477 kb)
Zhang, Yong; Sun, Wenxuan; Li, Chao:
Nickel-Catalyzed Paired Electrochemical Cross-Coupling of Aryl Halides with Nucleophiles
Full Text
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PDF (482 kb)
Fokin, Igor; Kuessner, Kai-Thorben; Siewert, Inke:
Transition Metal Complex Catalyzed Photo- and Electrochemical (De)hydrogenations Involving C=O and C=N Bonds
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PDF (816 kb)
Feng, Yanping; Ye, Xiajuan; Huang, Dayun; Guo, Sheng-rong:
α-Csp
3
–H Bond Functionalization of Simple Ethers in Radical Reactions
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PDF (720 kb)
Issue 01/2022
Cui, Shu-Qiang; Liao, Wei-Wei:
Recent Advances in Transition-Metal-Catalyzed C–H Addition to Nitriles
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PDF (578 kb)
He, Peng; Hu, Meng-Yang; Zhang, Xin-Yu; Zhu, Shou-Fei:
Transition-Metal-Catalyzed Stereo- and Regioselective Hydrosilylation of Unsymmetrical Alkynes
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PDF (636 kb)
Li, Qing-Zhu; Zou, Wen-Lin; Jia, Zhi-Qiang; Li, Jun-Long:
Recent Advances on Annulation Reactions with Allyl and Propargyl Sulfonium Salts
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PDF (657 kb)
Williams, Dean; Jamshidi, Mohammad P.; Sauvageau, Janelle:
Pathogen-Associated Molecular Patterns: The Synthesis of Heptose Phosphates and Derivatives
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PDF (443 kb)
Jia, Jie; Hu, Fangdong; Xia, Ying:
Transition-Metal-Catalyzed Nucleophilic Dearomatization of Electron-Deficient Heteroarenes
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PDF (707 kb)
Ghorai, Sourav; Lee, Daesung:
Strain-Induced Transformations of Bicyclo[3.1.0]hex-1-enes
Full Text
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PDF (596 kb)
Issue 24/2021
Melngaile, Renate; Veliks, Janis:
Synthetic Applications of Monofluoromethylsulfonium Salts
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PDF (489 kb)
Orlandi, Manuel; Escudero-Casao, Margarita; Licini, Giulia:
Transition-Metal-Catalyzed Enantioselective α-Arylation of Carbonyl Compounds to Give Tertiary Stereocenters
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PDF (768 kb)
Empel, Claire; Jana, Sripati; Koenigs, Rene M.:
Advances in [1,2]-Sigmatropic Rearrangements of Onium Ylides via Carbene Transfer Reactions
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PDF (691 kb)
Qin, Yu-Nan; Zhang, Chen; Li, Quan; Du, Guang-Yan:
Development of Synthetic Strategies to Access Optically Pure Feringa’s Motors
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PDF (504 kb)
Fontaine, Frédéric-Georges; Desrosiers, Vincent:
Boron Lewis Pair Mediated C–H Activation and Borylation
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PDF (776 kb)
Issue 23/2021
Varga, Bálint; Csenki, János T.; Tóth, Balázs L.; Béke, Ferenc; Novák, Zoltán; Kotschy, András:
Application of Industrially Relevant HydroFluoroOlefin (HFO) Gases in Organic Syntheses
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PDF (989 kb)
Xiong, Yang; Li, Sijia; Xiao, Haijing; Zhang, Guozhu:
Recent Advances in Visible-Light-Promoted Copper Catalysis in Organic Reactions
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PDF (635 kb)
Yu, Xinhui; Zhang, Ting; Liu, Jitian; Li, Xiaoxun:
Recent Advances in the Construction of Quaternary Stereocenters via Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation
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PDF (581 kb)
Uçar, Sefa; Daştan, Arif:
Recent Advances in the Transition-Metal-Free Arylation of Heteroarenes
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PDF (823 kb)
Liu, Le; Duan, Xin-Hua; Guo, Li-Na:
Recent Advance in Iminyl Radical Triggered C–H and C–C Bond Functionalization of Oxime Esters via 1,5-HAT and β-Carbon Scission
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PDF (859 kb)
Liao, Jin-Xi; Hu, Zhen-Ni; Liu, Hui; Sun, Jian-Song:
Advances in the Semi-Synthesis of Triterpenoids
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PDF (1007 kb)
Issue 21/2021
Sorrentino, Jacob P.; Altman, Ryan A.:
Fluorine-Retentive Strategies for the Functionalization of
gem
-Difluoroalkenes
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PDF (754 kb)
Tao, Zhong-Lin; Denmark, Scott E.:
Catalytic, Enantioselective Diamination of Alkenes
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PDF (552 kb)
Baumann, Marcus; Moody, Thomas S.; Smyth, Megan; Wharry, Scott:
Evaluating the Green Credentials of Flow Chemistry towards Industrial Applications
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PDF (1501 kb)
Liu, Weilong; Winssinger, Nicolas:
Synthesis of α-
exo
-Methylene-γ-butyrolactones: Recent Developments and Applications in Natural Product Synthesis
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PDF (1096 kb)
Armengol-Relats, Helena; Mato, Mauro; Escofet, Imma; Echavarren, Antonio M.:
Assembling Complex Structures through Cascade and Cycloaddition Processes via Non-Acceptor Gold or Rhodium Carbenes
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PDF (1083 kb)
Issue 20/2021
Fershtat, Leonid L.; Teslenko, Fedor E.:
Five-Membered Hetarene
N
-Oxides: Recent Advances in Synthesis and Reactivity
Full Text
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PDF (412 kb)
Wang, Zhan-Yong; Guo, Qi; Xu, Shaohong; Wang, Kai-Kai:
Nucleophilic H-Phosphites, H-Phosphinates, and H-Phosphine Oxides in Organic Reactions
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PDF (834 kb)
Ju, Guodong; Tu, Guanglian; Zhao, Yingsheng:
Recent Advances in Transition-Metal-Catalyzed Selective C–H Alkoxycarbonyldifluoromethylation Reactions of Aromatic Substrates
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PDF (776 kb)
Li, Shen-Huan; Long, Cheng-Yu; Yang, Xin-Ge; Wang, Xue-Qiang:
Recent Progress in Amination Enabled by Transition-Metal-Free C(sp
2
)–O/C(sp
2
)–S Bond Cleavage Strategy
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PDF (473 kb)
Issue 19/2021
Kieslich, David; Christoffers, Jens:
Cyanide Anions as Nucleophilic Catalysts in Organic Synthesis
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PDF (647 kb)
Slivka, Mikhailo; Onysko, Mikhailo:
The Use of Electrophilic Cyclization for the Preparation of Condensed Heterocycles
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PDF (673 kb)
Sako, Makoto; Arisawa, Mitsuhiro:
Recent Advances in Metal-Nanoparticle-Catalyzed Coupling Reactions Assisted by Microwave Irradiation
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PDF (478 kb)
Gao, Biwen; Deng, Danfeng; Huang, Dayun; Sun, Xiangyu:
Recent Advances in the Tandem Difunctionalization of Alkynes: Mechanism-Based Classification
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PDF (557 kb)
Issue 16/2021
Roche, Stéphane P.:
In the Pursuit of (Ald)Imine Surrogates for the Direct Asymmetric Synthesis of Non-Proteinogenic α-Amino Acids
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Majdecki, Maciej; Niedbała, Patryk; Tyszka-Gumkowska, Agata; Jurczak, Janusz:
Assisted by Hydrogen-Bond Donors:
Cinchona
Quaternary Salts as Privileged Chiral Catalysts for Phase-Transfer Reactions
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Zhang, Sheng; Findlater, Michael:
Cobalt-Catalyzed Isomerization of Alkenes
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Youssef-Saliba, Sparta; Vallée, Yannick:
Sulfur Amino Acids: From Prebiotic Chemistry to Biology and Vice Versa
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Issue 15/2021
Jurinic, Carla K.; Belladona, Andrei L.; Schumacher, Ricardo F.; Godoi, Benhur:
Diorganyl Dichalcogenides and Copper/Iron Salts: Versatile Cyclization System To Achieve Carbo- and Heterocycles from Alkynes
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Rubtsov, Aleksandr E.; Malkov, Andrei V.:
Recent Advances in the Synthesis of 2,2′-Bipyridines and Their Derivatives
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Zhang, Qiaoling; Xi, Jufang; Ze, He; Qingle, Zeng:
Syntheses and Transformations of Sulfinamides
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Rehpenn, Andreas; Walter, Alexandra; Storch, Golo:
Molecular Editing of Flavins for Catalysis
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Issue 14/2021
Pedrood, Keyvan; Montazer, Mohammad Nazari; Larijani, Bagher; Mahdavi, Mohammad:
Recent Advances in the Synthesis of Heterocycles by the Aza-Wittig Reaction
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Li, Qingjiang; Guo, Zhongwu:
Enzymatic Synthesis of Glycosphingolipids: A Review
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Kahlert, Lukas; Schotte, Carsten; Cox, Russell J.:
Total Mycosynthesis: Rational Bioconstruction and Bioengineering of Fungal Natural Products
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Livingstone, Keith; Little, Gemma; Jamieson, Craig:
Recent Advances in the Generation of Nitrilium Betaine 1,3-Dipoles
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Issue 13/2021
Liu, Jiaming; Chen, Ming:
1,3-Bifunctional Nucleophilic Allylation Reagents: Preparative Methods and Synthetic Applications
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Inoa, Joan; Dominici, Grecia; Eldabagh, Reem; Foley, Jonathan J.; Xing, Yalan:
Synthetic Applications and Computational Perspectives on Eosin Y Induced Direct HAT Process
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Issue 12/2021
Neri, Raul; Bossmann, Stefan H.:
Isoselenocyanates: Synthesis and Their Use for Preparing Selenium-Based Heterocycles
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Zu, Bing; Guo, Yonghong; Ke, Jie; He, Chuan:
Transient- and Native-Directing-Group-Enabled Enantioselective C–H Functionalization
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Issue 11/2021
Ashikari, Yosuke; Nagaki, Aiichiro:
Homogeneous Catalyzed Aryl–Aryl Cross-Couplings in Flow
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Issue 10/2021
Zhao, Jia-Jia; Zhang, Hong-Hao; Yu, Shouyun:
Enantioselective Radical Functionalization of Imines and Iminium Intermediates via Visible-Light Photoredox Catalysis
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Zheng, Songlin; Hu, Yuanyuan; Yuan, Weiming:
Recent Advances in C(sp
3
)–C(sp
3
) Cross-Coupling via Metallaphotoredox Strategies
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Mazumdar, Wrickban; Driver, Tom G.:
Recent Advances in the Development of Catalytic Methods that Construct Medium-Ring Lactams, Partially Saturated Benzazepines and Their Derivatives
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Issue 09/2021
Singh, Pushpinder; Batra, Aanchal; Singh, Kamal Nain; Mritunjay, Mritunjay:
Transition-Metal-Free Strategies for the Synthesis of C-1 Aryl-Substituted Tetrahydroisoquinolines
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Li, Yanjun; Ye, Ziqi; Cai, Jiaxin; Gong, Lei:
Visible-Light-Promoted Asymmetric Catalysis by Chiral Complexes of First-Row Transition Metals
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Issue 08/2021
Bartoccini, Francesca; Piersanti, Giovanni:
Synthesis and Reactivity of Uhle’s Ketone and Its Derivatives
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Yu, Hsien-Cheng; Mankad, Neal P.:
Catalytic Reactions by Heterobimetallic Carbonyl Complexes with Polar Metal–Metal Interactions
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Yu, Jingxun; Luan, Xinjun:
Hydroxylamines as One-Atom Nitrogen Sources for Metal-Catalyzed Cycloadditions
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Issue 07/2021
Zhao, Xuchen; Rainier, Jon D.:
The Synthesis of Conjugated Bis-Aryl Vinyl Substrates and Their Photoelectrocyclization Reactions towards Phenanthrene Derivatives
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Walther, Melanie; Kipke, Waldemar; Schultzke, Sven; Ghosh, Souvik; Staubitz, Anne:
Modification of Azobenzenes by Cross-Coupling Reactions
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Su, Shixia; Wang, Chuan:
Catalytic Asymmetric Osmium-Free Dihydroxylation of Alkenes
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Issue 06/2021
Cherepakhin, Valeriy; Williams, Travis J.:
Direct Oxidation of Primary Alcohols to Carboxylic Acids
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Jovanovic, Milos D.; Petkovic, Milos R.; Savic, Vladimir M.:
Polycyclic Compounds from Allenes via Palladium-Mediated Intramolecular Carbopalladation/Nucleophilic Substitution Cascade Processes
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Nejrotti, Stefano; Prandi, Cristina:
Gold Catalysis and Furans: A Powerful Match for Synthetic Connections
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Yang, Chao; Jiang, Chao; Qi, Xiangbing:
Alkylzirconocenes in Organic Synthesis: An Overview
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Issue 05/2021
Ura, Yasuyuki:
Palladium-Catalyzed Anti-Markovnikov Oxidation of Aromatic and Aliphatic Alkenes to Terminal Acetals and Aldehydes
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Gao, Shuangqiu; Shi, Lili; Chang, Le; Wang, Binglin; Fu, Junkai:
Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles
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Gale-Day, Zachary J.:
Recent Advances in Metal-Catalyzed, Electrochemical Coupling Reactions of sp
2
Halides/Boronic Acids and sp
3
Centers
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Wang, Yang; Yang, Bing; Wu, Xin-Xing; Wu, Zheng-Guang:
Recent Application of Chiral Aryliodine Based on the 2-Iodoresorcinol Core in Asymmetric Catalysis
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Issue 04/2021
Chen, Nuan; He, Min; Zhou, Ting; Zhu, Yuqi; Zhang, Hong; Peng, Shiyong:
Recent Advances in the Tandem Cyclization/Cycloaddition of Allene Intermediates from Copper-Catalyzed Cross-Coupling of Diazo Compounds with Terminal Alkynes
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Wang, Lili; Ma, Juan; Si, Erbing; Duan, Zheng:
Recent Advances in Luminescent Annulated Borepins, Silepins, and Phosphepins
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Xu, Ke; Wang, Ziyuan; Zhu, Tingshun:
Recent Progress towards Organocatalyzed Asymmetric (Hetero)Arene Formation
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Gonay, Marie; Batisse, Chloé; Paquin, Jean-François:
Recent Advances in the Synthesis of Acyl Fluorides
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Issue 03/2021
Némethová, Ivana; Šebesta, Radovan:
Are Organozirconium Reagents Applicable in Current Organic Synthesis?
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Clapham, Margaret L.; Murphy, Emma C.; Douglas, Christopher J.:
Synthesis and Crystal Engineering of Rubrene and Its Derivatives
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Jeon, Hongjun; Winkler, Jeffrey D.:
Synthesis of Cyclohexane-Angularly-Fused Triquinanes
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Saway, Jason; Salem, Zena M.; Badillo, Joseph J.:
Recent Advances in Photoacid Catalysis for Organic Synthesis
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Issue 02/2021
Zhang, Fulin; Xin, Luoting; Yu, Yinghua; Liao, Saihu; Huang, Xueliang:
Recent Advances in Palladium-Catalyzed Bridging C–H Activation by Using Alkenes, Alkynes or Diazo Compounds as Bridging Reagents
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Edlová, Tereza; Čubiňák, Marek; Tobrman, Tomáš:
Cross-Coupling Reactions of Double or Triple Electrophilic Templates for Alkene Synthesis
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Bandari, Chandrasekhar; Nicholas, Kenneth M.:
Deoxygenative Transition-Metal-Promoted Reductive Coupling and Cross-Coupling of Alcohols and Epoxides
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Magyar, Ágnes; Juhász, Kinga; Hell, Zoltán:
The Application of 4Å Molecular Sieves in Organic Chemical Syntheses: An Overview
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Issue 01/2021
Muñoz-Molina, José María; Belderrain, Tomás R.; Pérez, Pedro J.:
Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents
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Shoemaker, Aaron H.; Griffith, Daniel R.:
Synthetic Approaches to Non-Tropane, Bridged, Azapolycyclic Ring Systems Containing Seven-Membered Carbocycles
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Carreras, Virginie; Tanbouza, Nour; Ollevier, Thierry:
The Power of Iron Catalysis in Diazo Chemistry
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Chen, Tieqiao; Tan, Qihang; Liu, Xue; Liu, Long; Huang, Tianzeng; Han, Li-Biao:
Phosphorylation of Carboxylic Acids and Their Derivatives with P(O)–H Compounds Forming P(O)–C Bonds
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Macchia, Antonio; Eitzinger, Andreas; Brière, Jean-François; Waser, Mario; Massa, Antonio:
Asymmetric Synthesis of Isoxazol-5-ones and Isoxazolidin-5-ones
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Issue 24/2020
Chen, Jin-Quan; Dong, Zhi-Bing:
Recent Progress in Utilization of Functionalized Organometallic Reagents in Cross Coupling Reactions and Nucleophilic Additions
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Al Bujuq, Nader:
Methods of Synthesis of Remdesivir, Favipiravir, Hydroxychloroquine, and Chloroquine: Four Small Molecules Repurposed for Clinical Trials during the Covid-19 Pandemic
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Pang, Xiaobo; Peng, Xuejing; Shu, Xing-Zhong:
Reductive Cross-Coupling of Vinyl Electrophiles
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Talukdar, Ranadeep:
Synthetically Important Ring-Opening Acylations of Alkoxybenzenes
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Yu, Jie; Singh, Anoop S.; Yan, Guobing; Yu, Jian; Tiwari, Vinod K.:
Recent Developments on Denitrogenative Functionalization of Benzotriazoles
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Issue 23/2020
Gan, Fuqiang; Luo, Puying; Lin, Junyue; Ding, Qiuping:
Recent Advances in the Synthesis and Applications of 2-Arylbenzothiazoles
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Gao, Weiwei; Ding, Shengtao:
Progress on Iridium-Catalyzed Hydrosilylation of Alkenes and Alkynes
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Filippov, Ilya P.; Titov, Gleb D.; Rostovskii, Nikolai V.:
Recent Advances in Denitrogenative Reactions of Pyridotriazoles
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Khandelwal, Manisha; Ray, Sumit Kumar; Khangarot, Rama Kanwar:
Syntheses and Applications of Singh’s Catalyst
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Issue 22/2020
Yorimitsu, Hideki; Yoshimura, Aya; Misaki, Yohji:
Catalytic C–H Arylation of Tetrathiafulvalenes for the Synthesis of Functional Materials
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Li, Dan; Chen, Xiaochao; Gao, Wei:
Asymmetric Synthesis of C
1
-Chiral THIQs with Imines in Isoquinoline Rings
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Issue 21/2020
Mateus-Ruiz, Jeferson B.; Cordero-Vargas, Alejandro:
Visible-Light-Mediated Photoredox Reactions in the Total Synthesis of Natural Products
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Moberg, Christina:
Silylboranes as Powerful Tools in Organic Synthesis: Stereo- and Regioselective Reactions with 1,n-Enynes
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Issue 20/2020
Calcatelli, Alessio; Cherubini-Celli, Alessio; Carletti, Edoardo; Companyó, Xavier:
Unconventional Transformations of Morita–Baylis–Hillman Adducts
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Weißbarth, Hendrik; Mühlhaus, Felix; Gansäuer, Andreas:
Titanocene-Catalyzed Regiodivergent Epoxide Opening – From Desymmetrizing
meso
-Epoxides to Regiodivergent Arylation of Epoxides
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Zhao, Fei; Masci, Domiziana; Tomarelli, Elena; Castagnolo, Daniele:
Biocatalytic and Chemo-Enzymatic Approaches for the Synthesis of Heterocycles
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Issue 19/2020
Grygorenko, Oleksandr O.; Moskvina, Viktoriia S.; Hryshchuk, Oleksandr V.; Tymtsunik, Andriy V.:
Cycloadditions of Alkenylboronic Derivatives
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Geske, Leander; Sato, Eisuke; Opatz, Till:
Anodic Oxidation as an Enabling Tool for the Synthesis of Natural Products
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Arisawa, Mieko:
Transition-Metal-Catalyzed Synthesis of Organophosphorus Compounds Involving P–P Bond Cleavage
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Bottcher, Sydney E.; Hutchinson, Lauren E.; Wilger, Dale J.:
Nickel-Catalyzed
anti
-Selective Alkyne Functionalization Reactions
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Issue 18/2020
Large, Benjamin; Prim, Damien:
C–H Functionalization Strategies in the Naphthalene Series: Site Selections and Functional Diversity
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Almasalma, Ahmad A.; Mejía, Esteban:
Recent Advances on Copper-Catalyzed C–C Bond Formation via C–H Functionalization
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Agrawal, Toolika; Sieber, Joshua D.:
Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies
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Álvarez-Pérez, Andrea; Saá, Carlos; Varela, Jesús A.:
Oxidation of Alkynes via Catalytic Metal-Vinylidenes
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Issue 17/2020
Corti, Vasco; Bertuzzi, Giulio:
Organocatalytic Asymmetric Methodologies towards the Synthesis of Atropisomeric N-Heterocycles
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Liang, Dong; Xiao, Wen-Jing; Chen, Jia-Rong:
Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions
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Brechmann, Lea T.; Teichert, Johannes F.:
Catch It If You Can: Copper-Catalyzed (Transfer) Hydrogenation Reactions and Coupling Reactions by Intercepting Reactive Intermediates Thereof
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Beltran, Frédéric; Miesch, Laurence:
Tertiary Enamides as Versatile and Valuable Substrates to Reach Chemical Diversity
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Issue 16/2020
Yoshimura, Akira; Saito, Akio; Yusubov, Mekhman S.; Zhdankin, Viktor V.:
Synthesis of Oxazoline and Oxazole Derivatives by Hypervalent-Iodine-Mediated Oxidative Cycloaddition Reactions
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Liu, Xue; Wu, Xiangmei; Zhang, Ling; Lin, Xiaoyan; Huang, Dayun:
Recent Advances in Triarylmethane Synthesis
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Issue 15/2020
Beļaunieks, Rūdolfs; Puriņš, Mikus; Turks, Māris:
Manifestation of the β-Silicon Effect in the Reactions of Unsaturated Systems Involving a 1,2-Silyl Shift
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Smolobochkin, Andrey V.; Gazizov, Almir S.; Turmanov, Rakhymzhan A.; Abdullaeva, Dinara S.; Burilov, Alexander R.; Pudovik, Michail A.:
N
-Phosphorylated Pyrrolidines: An Overview of Synthetic Approaches
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Issue 14/2020
Mittersteiner, Mateus; Bonacorso, Helio G.; Martins, Marcos A. P.; Zanatta, Nilo:
Brominated β-Alkoxyvinyl Trihalomethyl Ketones as Promising Synthons in Heterocyclic Synthesis
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Kramer, Søren:
Homogeneous Gold-Catalyzed Aryl–Aryl Coupling Reactions
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Issue 13/2020
Danilkina, Natalia A.; Govdi, Anastasia I.; Balova, Irina A.:
5-Iodo-1
H
-1,2,3-triazoles as Versatile Building Blocks
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Issue 12/2020
Chai, Zhuo:
Catalytic Asymmetric Transformations of Racemic Aziridines
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Issue 11/2020
Khan, Muhammad Kamran; Wang, Dandan; Moloney, Mark G.:
Functionalised Nitrogen Heterocycles and the Search for New Antibacterials and Bioactives
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Fischer, Jérôme; Nun, Pierrick; Coeffard, Vincent:
Visible-Light-Driven Transformations of Phenols via Energy Transfer Catalysis
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Issue 10/2020
Woltornist, Ryan A.; Ma, Yun; Algera, Russell F.; Zhou, Yuhui; Zhang, Zirong; Collum, David B.:
Structure, Reactivity, and Synthetic Applications of Sodium Diisopropylamide
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Issue 09/2020
Tu, Hai-Yong; Zhu, Shengqing; Qing, Feng-Ling; Chu, Lingling:
Recent Advances in Nickel-Catalyzed Three-Component Difunctionalization of Unactivated Alkenes
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Zheng, Yue; Shao, Xiaoqing; Ramadoss, Velayudham; Tian, Lifang; Wang, Yahui:
Recent Developments in Photochemical and Electrochemical Decarboxylative C(sp
3
)–N Bond Formation
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Issue 08/2020
Zhu, Yannan; Huang, You:
Organocatalyzed [3+3] Annulations for the Construction of Heterocycles
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Issue 07/2020
Salom-Roig, Xavier; Bauder, Claude:
Recent Applications in the Use of Sulfoxides as Chiral Auxiliaries for the Asymmetric Synthesis of Natural and Biologically Active Products
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Ping, Yuanyuan; Kong, Wangqing:
Ni-Catalyzed Reductive Difunctionalization of Alkenes
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Kuang, Guanghua; Liu, Guangyuan; Zhang, Xingxing; Lu, Naihao; Peng, Yiyuan; Xiao, Qiang; Zhou, Yirong:
Directing-Group-Assisted Transition-Metal-Catalyzed Direct C–H Oxidative Annulation of Arenes with Alkynes for Facile Construction of Various Oxygen Heterocycles
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Issue 06/2020
Song, Si-Zhe; Dong, Youren; Ge, Guo-Ping; Li, Qiang; Wei, Wen-Ting:
Recent Advances in Radical Nitration Using
tert
-Butyl Nitrite
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Youn, So Won:
Transition-Metal-Catalyzed Annulative Coupling Cascade for the Synthesis of 3-Methyleneisoindolin-1-ones
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Hsieh, Jen-Chieh; Su, Haw-Lih:
Synthesis of
N
-Heterocycles via Transition-Metal-Catalyzed Tandem Addition/Cyclization of a Nitrile
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Issue 05/2020
Akkarasamiyo, Sunisa; Ruchirawat, Somsak; Ploypradith, Poonsaksi; Samec, Joseph S. M.:
Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols
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Fatykhov, Ramil F.; Chupakhin, Oleg N.; Inyutina, Anna K.; Khalymbadzha, Igor A.:
Synthetic Approaches to Unsymmetrically Substituted 5,7-Dihydroxycoumarins
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Meng, Yan-Ping; Wang, Shi-Meng; Fang, Wan-Yin; Xie, Zhi-Zhong; Leng, Jing; Alsulami, Hamed; Qin, Hua-Li:
Ethenesulfonyl Fluoride (ESF) and Its Derivatives in SuFEx Click Chemistry and More
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Issue 04/2020
Uttry, Alexander; van Gemmeren, Manuel:
Direct C(sp
3
)–H Activation of Carboxylic Acids
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Pang, Yue; Moser, Daniel; Cornella, Josep:
Pyrylium Salts: Selective Reagents for the Activation of Primary Amino Groups in Organic Synthesis
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Baráth, Eszter:
Selective Reduction of Carbonyl Compounds via (Asymmetric) Transfer Hydrogenation on Heterogeneous Catalysts
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Issue 03/2020
Nocera, Giuseppe; Murphy, John A.:
Ground State Cross-Coupling of Haloarenes with Arenes Initiated by Organic Electron Donors, Formed in situ: An Overview
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Smyshliaeva, Lidiia A.; Varaksin, Mikhail V.; Charushin, Valery N.; Chupakhin, Oleg N.:
Azaheterocyclic Derivatives of
ortho
-Carborane: Synthetic Strategies and Application Opportunities
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De Luca, Lorena; Mezzetti, Antonio:
Catalytic Strategies to Enantiopure Benzoins: Past and Future
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Daley, Ryan A.; Topczewski, Joseph J.:
Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism
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Issue 02/2020
Skotnitzki, Juri; Kremsmair, Alexander; Knochel, Paul:
Stereoselective Preparation and Reactions of Chiral Secondary Alkyllithiums
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Xiao, Xuan; Zheng, Zi-Tong; Li, Ting; Zheng, Jing-Lin; Tao, Ting; Chen, Li-Mei; Gu, Jin-Ying; Yao, Xu; Lin, Jin-Hong; Xiao, Ji-Chang:
Recent Advances in Difluoromethylthiolation
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Issue 01/2020
Baidilov, Daler:
On the Mechanism of the Stevens Rearrangement
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Craig, Alexander J.; Hawkins, Bill C.:
The Bonding and Reactivity of α-Carbonyl Cyclopropanes
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Issue 24/2019
Zhang, Tong; Wu, Yue-Hua; Wang, Nai-Xing; Xing, Yalan:
Advances in C(sp
3
)–H Bond Functionalization via Radical Processes
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Levi, Noam; Amir, Dafna; Gershonov, Eytan; Zafrani, Yossi:
Recent Progress on the Synthesis of CF
2
H-Containing Derivatives
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Issue 23/2019
Rakitin, Oleg A.:
Recent Developments in the Synthesis of 1,2,5-Thiadiazoles and 2,1,3-Benzothiadiazoles
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Issue 22/2019
Zeidan, Nicolas; Lautens, Mark:
Migratory Insertion Strategies for Dearomatization
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Issue 21/2019
Allouche, Emmanuelle M. D.; Charette, André B.:
Cyclopropanation Reactions of Semi-stabilized and Non-stabilized Diazo Compounds
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Issue 20/2019
Li, Yuyang; Kluger, Ronald:
Metal-Catalyzed Site-Selective Monoacylation of Diols in Aqueous Media
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Issue 19/2019
Rossignon, Alexandre; Bonifazi, Davide:
O-Annulation Leading to Five-, Six-, and Seven-Membered Cyclic Diaryl Ethers Involving C–H Cleavage
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Issue 18/2019
Gazizov, Almir S.; Smolobochkin, Andrey V.; Turmanov, Rahimjan A.; Pudovik, Michail A.; Burilov, Alexander R.; Sinyashin, Oleg G.:
Synthesis of Phosphaproline Derivatives: A Short Overview
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Issue 14/2019
Senatore, Raffaele; Ielo, Laura; Monticelli, Serena; Castoldi, Laura; Pace, Vittorio:
Weinreb Amides as Privileged Acylating Agents for Accessing α-Substituted Ketones
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Mudarra, Ángel L.; Martínez de Salinas, Sara; Pérez-Temprano, Mónica H.:
Nucleophilic Trifluoromethylation Reactions Involving Copper(I) Species: From Organometallic Insights to Scope
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Herraiz, Ana G.; Suero, Marcos G.:
New Alkene Cyclopropanation Reactions Enabled by Photoredox Catalysis via Radical Carbenoids
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Kunfi, Attila; London, Gábor:
Polydopamine: An Emerging Material in the Catalysis of Organic Transformations
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Issue 13/2019
Steven, Alan:
Micelle-Mediated Chemistry in Water for the Synthesis of Drug Candidates
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Issue 12/2019
Sbei, Najoua; Listratova, Anna V.; Titov, Alexander A.; Voskressensky, Leonid G.:
Recent Advances in Electrochemistry for the Synthesis of
N
-Heterocycles
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Issue 11/2019
Wang, Zhang:
The Chemical Syntheses of Nannocystins
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Hollanders, Karlijn; Maes, Bert U. W.; Ballet, Steven:
A New Wave of Amide Bond Formations for Peptide Synthesis
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Issue 10/2019
Colomban, Cédric; Châtelet, Bastien; Martinez, Alexandre:
Different Strategies for Obtaining Enantiopure Hemicryptophanes
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Li, Jie; Knochel, Paul:
Chromium-Catalyzed Cross-Couplings and Related Reactions
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Issue 09/2019
Parisotto, Stefano; Deagostino, Annamaria:
π-Allylpalladium Complexes in Synthesis: An Update
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Kotha, Sambasivarao; Meshram, Milind; Panguluri, Nageswara Rao:
Advanced Approaches to Post-Assembly Modification of Peptides by Transition-Metal-Catalyzed Reactions
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Rodriguez, Jean; Quintard, Adrien:
Acyl Transfer Strategies as Transient Activations for Enantioselective Synthesis
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Issue 08/2019
Eschliman, Kayla; Bossmann, Stefan H.:
Synthesis of Isothiocyanates: An Update
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D’Hollander, Agathe C. A.; Peilleron, Laure; Grayfer, Tatyana D.; Cariou, Kevin:
Halonium-Induced Polyene Cyclizations
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Issue 07/2019
Vasilenko, Dmitry A.; Sedenkova, Kseniya N.; Kuznetsova, Tamara S.; Averina, Elena B.:
Synthetic Approaches to Nitro-Substituted Isoxazoles
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Usman, Muhammad; Zhang, Xiao-Wen; Liu, Wen-Bo:
Silicon-Tethered Frameworks as Directing Groups for Carbon–Carbon and Carbon–Heteroatom Bond Formation
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Issue 06/2019
Pellissier, Hélène:
Synthesis of Chiral 3-Substituted 3-Amino-2-oxindoles through Enantioselective Catalytic Domino and Tandem Reactions
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Michelotti, Alessia; Roche, Maxime:
40 Years of Hydrogen–Deuterium Exchange Adjacent to Heteroatoms: A Survey
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Issue 05/2019
Zard, Samir Z.:
Sulfur Betaines from
S
-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group
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Crawford, Jennifer M.; Sigman, Matthew S.:
Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?
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Ferrer, Sofia; Echavarren, Antonio M.:
Synthesis of Bullvalenes: Classical Approaches and Recent Developments
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Maraswami, Manikantha; Loh, Teck-Peng:
Transition-Metal-Catalyzed Alkenyl sp
2
C–H Activation: A Short Account
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Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.:
Advancements in Visible-Light-Enabled Radical C(sp)
2
–H Alkylation of (Hetero)arenes
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Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline:
Pyrroles as Dienes in (4+3) Cycloadditions
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Gagosz, Fabien:
Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry
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Groso, Emilia J.; Schindler, Corinna S.:
Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles
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Issue 04/2019
Leonardi, Marco; Estévez, Verónica; Villacampa, Mercedes; Menéndez, J. Carlos:
The Hantzsch Pyrrole Synthesis: Non-conventional Variations and Applications of a Neglected Classical Reaction
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Palmieri, Alessandro; Petrini, Marino:
Recent Advances in the Synthesis of Unsymmetrical Bisindolylmethane Derivatives
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Issue 03/2019
Vaitla, Janakiram; Bayer, Annette:
Sulfoxonium Ylide Derived Metal Carbenoids in Organic Synthesis
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Hrdina, Radim:
Directed C–H Functionalization of the Adamantane Framework
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Kancherla, Sindhu; Jørgensen, Kåre B.; Fernández-Ibáñez, M. Ángeles:
Recent Developments in Palladium-Catalysed Non-Directed C–H Bond Activation in Arenes
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Issue 02/2019
Ghosh, Manoj K.; Rajkiewicz, Adam A.; Kalek, Marcin:
Organocatalytic Group Transfer Reactions with Hypervalent Iodine Reagents
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Singh, Kuldeep; Kulbir, Kulbir; Gupta, Tarang; Kaur, Rajneesh; Singh, Raman:
Applications of Rozen’s Reagent in Oxygen-Transfer and C–H Activation Reactions
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Passador, Kevin; Thorimbert, Serge; Botuha, Candice:
‘Heteroaromatic Rings of the Future’: Exploration of Unconquered Chemical Space
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Issue 01/2019
Murai, Masahito; Takai, Kazuhiko:
Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis
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Karageorgis, George; Waldmann, Herbert:
Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes
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Barrett, Anthony G. M.; Ma, Tsz-Kan; Mies, Thomas:
Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis
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Zhang, Heng; Lei, Aiwen:
Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H
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Piccardi, Riccardo; Turcaud, Serge; Benedetti, Erica; Micouin, Laurent:
Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents
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Kiefer, Alexander; Kazmaier, Uli:
Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis
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Wu, Xiang; Gong, Liu-Zhu:
Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective
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Yoshikai, Naohiko:
Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species
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Erb, William; Mongin, Florence:
Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations
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Lübken, Dennis; Saxarra, Marius; Kalesse, Markus:
Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
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Barde, E.; Guérinot, A.; Cossy, J.:
α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions
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Kumagai, Naoya; Shibasaki, Masakatsu:
7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C–C Bond-Forming Catalysis
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Issue 24/2018
Soorukram, Darunee; Pohmakotr, Manat; Kuhakarn, Chutima; Reutrakul, Vichai:
Stereoselective Synthesis of Tetrahydrofuran Lignans
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Barthelemy, Anne-Laure; Magnier, Emmanuel; Dagousset, Guillaume:
Direct Trifluoromethylthiolation Reactions Involving Radical Processes
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Schettini, Rosaria; Sicignano, Marina; De Riccardis, Francesco; Izzo, Irene; Della Sala, Giorgio:
Macrocyclic Hosts in Asymmetric Phase-Transfer Catalyzed Reactions
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Issue 23/2018
Martinez de Marigorta, Edorta; de los Santos, Jesús M.; Ochoa de Retana, Ana M.; Vicario, Javier; Palacios, Francisco:
Multicomponent Reactions in the Synthesis of γ-Lactams
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Cholewiak, Agnieszka; Stepniak, Pawel; Jurczak, Janusz:
Linear Neutral Receptors for Anions: Synthesis, Structure and Applications
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Jin, Tian; Zhao, Lu; Liu, Xiao; Sun, Liang; Lin, Jia-Fu; Zheng, Zhe-Bin:
Recent Advances in the Total Synthesis of Clavaminols
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Issue 21/2018
Roulland, Emmanuel:
Tiacumicin B: An Antibiotic of Prime Importance and a Natural Product with an Inspiring Complex Structure
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Dimitrov, Ivaylo; Denny, William A.; Jose, Jiney:
Syntheses of Ketamine and Related Analogues: A Mini Review
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Yuan, Yu-Chao; Bruneau, Christian; Gramage-Doria, Rafael:
Merging Transition-Metal Catalysis with Phthalimides: A New Entry to Useful Building Blocks
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Issue 20/2018
Gamba-Sánchez, Diego; Prunet, Joëlle:
Synthesis of 1,3-Diols by
O
-Nucleophile Additions to Activated Alkenes
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Nielsen, Christian D.-T.; Abas, Hossay; Spivey, Alan C.:
Stereoselective Reactions of
ortho
-Quinone Methide and
ortho
-Quinone Methide Imines and Their Utility in Natural Product Synthesis
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Hernández-Ruiz, Raquel; Sanz, Roberto:
Dichlorodioxomolybdenum(VI) Complexes: Useful and Readily Available Catalysts in Organic Synthesis
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Issue 19/2018
Ručilová, Veronika; Soural, Miroslav:
Recent Advances in the Applications of Triethylsilane in Organic Synthesis
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Rivera-Chao, Eva; Fra, Laura; Fañanás-Mastral, Martín:
Synergistic Bimetallic Catalysis for Carboboration of Unsaturated Hydrocarbons
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Dimitrov, Vladimir; Woodward, Simon:
Capturing Waste Heat Energy with Charge-Transfer Organic Thermoelectrics
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Chen, Jing-Biao; Whiting, Andrew:
Recent Advances in Copper-Catalyzed Asymmetric Hydroboration of Electron-Deficient Alkenes: Methodologies and Mechanism
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Issue 18/2018
Guyon, Hélène; Boussonnière, Anne; Castanet, Anne-Sophie:
Transition-Metal-Free Enantioselective Reactions of Organomagnesium Reagents Mediated by Chiral Ligands
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Oulyadi, Hassan:
Recent Advances in NMR: Aggregation, Solvation, and Dynamics of Selected Organolithium Compounds
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Brikci-Nigassa, Nahida Mokhtari; Bentabed-Ababsa, Ghenia; Erb, William; Mongin, Florence:
In Situ ‘Trans-Metal Trapping’: An Efficient Way to Extend the Scope of Aromatic Deprotometalation
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Smith, Keith; Alshammari, Mohammed B.; El-Hiti, Gamal A.:
Unravelling Factors Affecting Directed Lithiation of Acylaminoaromatics
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Plasseraud, Laurent:
Organotin(IV) Complexes Containing Sn–O–Se Moieties: A Structural Inventory
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Dagorne, Samuel:
Recent Developments on
N
-Heterocyclic Carbene Supported Zinc Complexes: Synthesis and Use in Catalysis
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Issue 16/2018
Listunov, Dymytrii; Joly, Etienne; Rullière, Pauline; Gaspard, Hafida; Bernardes-Génisson, Vania; Génisson, Yves; Maraval, Valérie; Chauvin, Remi:
From Natural to Artificial Antitumor Lipidic Alkynylcarbinols: Asymmetric Synthesis, Enzymatic Resolution, and Refined SARs
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Issue 15/2018
Segundo, Marcos San; Correa, Arkaitz:
Cross-Dehydrogenative Coupling Reactions for the Functionalization of α-Amino Acid Derivatives and Peptides
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Dhara, Ayan; Beuerle, Florian:
Synthetic Strategies for the Regioselective Functionalization of Tribenzotriquinacenes
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Issue 14/2018
Gomes, Ana T. P. C.; Forezi, Luana da S. M.; Simões, Mário M. Q.; Gonzaga, Daniel T.; Cardoso, Mariana F. C.; Da Silva, Fernando de C.; Neves, Maria G. P. M. S.; Ferreira, Vítor F.; Cavaleiro, José A. S.:
Carbene-Type Species in the Functionalization of Porphyrin Derivatives
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Leitch, Jamie A.; Frost, Christopher G.:
Regioselective Transition-Metal-Catalyzed C–H Functionalization of Anilines
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Riley, Darren L.; Neyt, Nicole C.:
Approaches for Performing Reductions under Continuous-Flow Conditions
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Issue 13/2018
Dalpozzo, Renato; Mancuso, Raffaella:
Enantioselective Vinylogous Reactions of 3-Alkylidene Oxindoles
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da Silva, Amanda F.; Fernandes, Alessandra A. G.; Thurow, Samuel; Stivanin, Mateus L.; Jurberg, Igor D.:
Isoxazol-5-ones as Strategic Building Blocks in Organic Synthesis
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Issue 12/2018
Kirupakaran, Sujenth; Korth, Hans-Gert; Hirschhäuser, Christoph:
A Complementary Toolbox of Iterative Methods for the Stereoselective Synthesis of Heteroatom-Rich Motives from C
1
-Building Blocks
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Bergman, Jan:
Comparison of Two Reagents for Thionations
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Issue 11/2018
Murarka, Sandip; Antonchick, Andrey P.:
Metal-Catalyzed Oxidative Coupling of Ketones and Ketone Enolates
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Botubol-Ares, José Manuel; Durán-Peña, María Jesús; Hanson, James R.; Hernández-Galán, Rosario; Collado, Isidro G.:
Cp
2
Ti(III)Cl and Analogues as Sustainable Templates in Organic Synthesis
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Issue 10/2018
Wu, Wei; Weng, Zhiqiang:
Synthesis of Aryl Trifluoromethyl Ketones
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Issue 09/2018
Silva, Eduarda M. P.; Rocha, Djenisa H. A.; Silva, Artur M. S.:
Diels–Alder Reactions of 1,2-Dihydropyridines: An Efficient Tool for the Synthesis of Isoquinuclidines
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Fasano, Valerio; Ingleson, Michael J.:
Recent Advances in Water-Tolerance in Frustrated Lewis Pair Chemistry
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Issue 08/2018
Mousavizadeh, Farnoush; Meyer, Daniel; Giannis, Athanassios:
Synthesis of C-Nor-D-homo-steroidal Alkaloids and Their Derivatives
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Bogdanov, Andrei V.; Mironov, Vladimir F.:
Advances in the Synthesis of Isatins: A Survey of the Last Decade
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Issue 07/2018
Boyle, Joshua William; Zhao, Yichao; Chan, Philip Wai Hong:
Product Divergence in Coinage-Metal-Catalyzed Reactions of π-Rich Compounds
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Méndez, María V.; Bracca, Andrea B. J.; Kaufman, Teodoro S.:
Isolation, Synthesis, and Biological Activity of Quindoline, a Valuable Indoloquinoline Natural Product and Useful Key Intermediate
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Issue 06/2018
Bürglová, Kristýna; Hlaváč, Jan:
Application of Trimethylsilanolate Alkali Salts in Organic Synthesis
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Albano, Gianluigi; Aronica, Laura Antonella:
Cyclization Reactions for the Synthesis of Phthalans and Isoindolines
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Meanwell, Michael; Britton, Robert:
Synthesis of Heterobenzylic Fluorides
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Issue 05/2018
Wang, Pu-Sheng; Shen, Meng-Lan; Gong, Liu-Zhu:
Transition-Metal-Catalyzed Asymmetric Allylation of Carbonyl Compounds with Unsaturated Hydrocarbons
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Balasubramaniam, Sivaraman; Sankaran, Ganapathy Subramanian; Badle, Sneh Sanjay:
Perspective on FTY720, an Immunosuppressant
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Chardon, Aurélien; Morisset, Eléonore; Rouden, Jacques; Blanchet, Jérôme:
Recent Advances in Amide Reductions
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Issue 04/2018
Ohno, Hiroaki; Inuki, Shinsuke:
Recent Progress in Palladium-Catalyzed Cascade Cyclizations for Natural Product Synthesis
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Li, Pengfei; Jia, Xiaodong:
tert
-Butyl Nitrite (TBN) as a Versatile Reagent in Organic Synthesis
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Len, Christophe; Delbecq, Frederic; Cara Corpas, Cristobal; Ruiz Ramos, Encarnacion:
Continuous Flow Conversion of Glycerol into Chemicals: An Overview
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Issue 03/2018
Martín-Heras, Víctor; Parra, Alejandro; Tortosa, Mariola:
Cyclopropyl- and Cyclobutylboronates and -silanes: A Stereoselective Approach
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Kiyokawa, Kensuke; Nagata, Takaya; Minakata, Satoshi:
Recent Advances in the Synthesis of β-Ketonitriles
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Richmond, Edward; Moran, Joseph:
Recent Advances in Nickel Catalysis Enabled by Stoichiometric Metallic Reducing Agents
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Issue 02/2018
Ramesh, Perla; Suman, Devatha; Reddy, Koti Siva Nagi:
Asymmetric Synthetic Strategies of (
R
)-(–)-Baclofen: An Antispastic Drug
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Vorobyeva, Daria V.; Osipov, Sergey N.:
Selective Synthesis of 2- and 7-Substituted Indole Derivatives via Chelation-Assisted Metallocarbenoid C–H Bond Functionalization
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Largeron, Martine; Nguyen, Khac Minh Huy:
Recent Advances in the Synthesis of Benzimidazole Derivatives from the Oxidative Coupling of Primary Amines
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Issue 01/2018
Ajay, Sama; Shaw, Arun K.:
Studies Towards the Synthesis of (+)- and (–)-Anisomycin and Their Analogues
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PDF (594 kb)
Chen, Yue-Gang; Xu, Xue-Tao; Zhang, Kun; Li, Yi-Qian; Zhang, Li-Pu; Fang, Ping; Mei, Tian-Sheng:
Transition-Metal-Catalyzed Carboxylation of Organic Halides and Their Surrogates with Carbon Dioxide
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Eivgi, Or; Lemcoff, N. Gabriel:
Turning the Light On: Recent Developments in Photoinduced Olefin Metathesis
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Issue 24/2017
Castro-Alvarez, Alejandro; Carneros, Héctor; Costa, Anna M; Vilarrasa, Jaume:
Computer-Aided Insight into the Relative Stability of Enamines
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Wang, Chuan:
Electrophilic Ring Opening of Small Heterocycles
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Issue 23/2017
Pankova, Alena S.; Kuznetsov, Mikhail A.:
Recent Advances in the Chemistry of 2-Acylaziridines
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Kimura, Tsutomu:
Recent Advances in Magnesium Carbenoid Chemistry
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Issue 22/2017
Hu, Wen-Li; Hu, Xiang-Guo; Hunter, Luke:
Recent Developments in the Deoxyfluorination of Alcohols and Phenols: New Reagents, Mechanistic Insights, and Applications
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Pathipati, Stalin R.; van der Werf, Angela; Selander, Nicklas:
Indium(III)-Catalyzed Transformations of Alkynes: Recent Advances in Carbo- and Heterocyclization Reactions
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Issue 21/2017
Gusarova, Nina K.; Chernysheva, Nataliya A.; Trofimov, Boris A.:
Catalyst- and Solvent-Free Addition of the P–H Species to Alkenes and Alkynes: A Green Methodology for C–P Bond Formation
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Zhao, Qun; Poisson, Thomas; Pannecoucke, Xavier; Besset, Tatiana:
The Transient Directing Group Strategy: A New Trend in Transition-Metal-Catalyzed C–H Bond Functionalization
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Issue 20/2017
Aziz, Jessy; Piguel, Sandrine:
An Update on Direct C–H Bond Functionalization of Nitrogen-Containing Fused Heterocycles
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Henry, Martyn C.; Mostafa, Mohamed A. B.; Sutherland, Andrew:
Recent Advances in Transition-Metal-Catalyzed, Directed Aryl C–H/N–H Cross-Coupling Reactions
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Issue 19/2017
Feng, Minghao; Jiang, Xuefeng:
Reactions of Arynes Involving Transition-Metal Catalysis
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Barroso, Raquel; Cabal, María P.; Valdés, Carlos:
Pd-catalyzed Auto-Tandem Cascades Based on
N
-Sulfonylhydrazones: Hetero- and Carbocyclization Processes
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Issue 18/2017
Míguez-Lago, Sandra; Cid, María Magdalena:
Axially Chiral Shape-Persistent Encapsulating Agents
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Issue 17/2017
Guo, Qihang; Lu, Zhan:
Recent Advances in Nitrogen–Nitrogen Bond Formation
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Pfund, Emmanuel; Lequeux, Thierry:
Synthesis of Fluoropyrrolidines and (Fluoroalkyl)pyrrolidines
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Issue 16/2017
Arava, Shlomy; Diesendruck, Charles E.:
Strategies for the Synthesis of
N
-Arylammonium Salts
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Issue 15/2017
Chen, Yi-Hung; Ellwart, Mario; Malakhov, Vladimir; Knochel, Paul:
Solid Organozinc Pivalates: A New Class of Zinc Organometallics with Greatly Enhanced Air- and Moisture-Stability
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Breugst, Martin; von der Heiden, Daniel; Schmauck, Julie:
Novel Noncovalent Interactions in Catalysis: A Focus on Halogen, Chalcogen, and Anion-π Bonding
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Bartolo, Nicole D.; Read, Jacquelyne A.; Valentín, Elizabeth M.; Woerpel, K. A.:
Reactions of Allylmagnesium Halides with Carbonyl Compounds: Reactivity, Structure, and Mechanism
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Mąkosza, Mieczysław:
How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism
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Tabolin, Andrey A.; Sukhorukov, Alexey Yu.; Ioffe, Sema L.; Dilman, Alexander D.:
Recent Advances in the Synthesis and Chemistry of Nitronates
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Parchomyk, Tobias; Koszinowski, Konrad:
Iron-Catalyzed Cross-Coupling: Mechanistic Insight for Rational Applications in Synthesis
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Dana, Suman; Ramakrishna, Isai; Baidya, Mahiuddin:
Ambident Reactivity of Nitroso Compounds for Direct Amination and Hydroxylation of Carbonyls
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Reissig, Hans-Ulrich; Zimmer, Reinhold:
Cyclizations of Alkoxyallenes: Mechanisms, Intermediates, Products – A Personal Account on Solved and Unsolved Problems with Unique Allene Building Blocks
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Hartley, Will C.; O’Riordan, Timothy J. C.; Smith, Andrew D.:
Aryloxide-Promoted Catalyst Turnover in Lewis Base Organocatalysis
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Fantin, Marco; Lorandi, Francesca; Gennaro, Armando; Isse, Abdirisak A.; Matyjaszewski, Krzysztof:
Electron Transfer Reactions in Atom Transfer Radical Polymerization
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Armstrong, Roly J.; Aggarwal, Varinder K.:
50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling
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Abe, Manabu; Chitose, Youhei; Jakkampudi, Satish; Thuy, Pham Thi Thu; Lin, Qianghua; Van, Bui Thi; Yamada, Ayato; Oyama, Ryoko; Sasaki, Miyu; Katan, Claudine:
Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions
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Micheletti, Gabriele; Boga, Carla:
Nucleophile/Electrophile Combinations in Aromatic Substitution: From Wheland to Wheland–Meisenheimer Intermediates Using Strongly Activated Arenes
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Zhao, Rong; Chang, Denghu; Shi, Lei:
Recent Advances in Cyclic Diacyl Peroxides: Reactivity and Selectivity Enhancement Brought by the Cyclic Structure
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Asahara, Haruyasu:
Recent Advances in the Carbon–Carbon Bond-Forming Reactions of
N
-Acylketimines
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Maji, Biplab; Barman, Milan K.:
Recent Developments of Manganese Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions
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Krishnamoorthy, Sankarganesh; Prakash, G. K. Surya:
Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions
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Gao, Pin; Gu, Yu-Rui; Duan, Xin-Hua:
Direct C–H Functionalization of Heteroarenes via Redox-Neutral Radical Process: A Facile Route to C–C Bonds Formation
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Denegri, Bernard; Matić, Mirela; Kronja, Olga:
Impact of Electronic Effects on the Nucleofugality of Leaving Groups
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Gualandi, Andrea; Mengozzi, Luca; Cozzi, Pier Giorgio:
Stereoselective S
N
1-Type Reaction of Enols and Enolates
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Quint, Valentin; Noël-Duchesneau, Ludovik; Lagadic, Elodie; Morlet-Savary, Fabrice; Lalevée, Jacques; Gaumont, Annie- Claude; Lakhdar, Sami:
Metal-Free Generation of Phosphorus-Centered Radicals for the Synthesis of Phosphorus-Based Heterocycles: A Personal Account
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Issue 14/2017
Budynina, Ekaterina M.; Ivanov, Konstantin L.; Sorokin, Ivan D.; Melnikov, Mikhail Ya.:
Ring Opening of Donor–Acceptor Cyclopropanes with
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-Nucleophiles
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Keglevich, György; Kiss, Nóra Zsuzsa; Grün, Alajos; Bálint, Erika; Kovács, Tamara:
Advantages of the Microwave Tool in Organophosphorus Syntheses
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