Synthesis, Table of Contents Synthesis 2023; 55(11): 1744-1751DOI: 10.1055/a-1970-4584 paper Special Issue dedicated to Prof. Cristina Nevado, recipient of the 2021 Dr. Margaret Faul Women in Chemistry Award Borylation of Alkenyl Carbamates by Means of Sodium Metal Authors Shunsuke Koyama Fumiya Takahashi Hayate Saito Hideki Yorimitsu ∗ Recommend Article Abstract Buy Article(opens in new window) All articles of this category(opens in new window) Abstract Treatment of alkenyl carbamates with sodium dispersion and a co-existing boron electrophile affords alkenylboronates via the reductive cleavage of the vinylic C–O bond. The key to this borylation is an instant trapping of reactive organosodium species with the co-existing boron electrophile. 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Chem. 2015; 80: 6715 Supplementary Material Supplementary Material Supporting Information (PDF) (opens in new window)
