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Synfacts 2017; 13(11): 1153
DOI: 10.1055/s-0036-1591339
DOI: 10.1055/s-0036-1591339
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
Ruthenium-Catalyzed Cycloaddition of Benzocyclobutenones with Diols
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
19. Oktober 2017 (online)
Significance
The authors have reported intermolecular cycloadditions through formal insertion of saturated C–H bonds into C–C σ-bonds. A ruthenium(0)/dppp complex catalyzed the diastereoselective coupling reactions of benzocyclobutenones to adjacent saturated carbon centers in diols.
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Comment
The cycloaddition via ruthenacycles from the benzocyclobutenones and dehydrogenation of the alcohols provides a convergent method for the construction of type II polyketide substructures.
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