DOI: 10.1055/s-00000083

Synlett

Issue 01 · Volume 26 · January 2015 DOI: 10.1055/s-004-28259

editorial

I
Editorial

synform

A1
Zanda, Matteo: SYNFORM ISSUE 2015/01

synpacts

1
Glas, Adrian; Grossmann, Tom N.: Constraining Peptide Conformations with the Help of Ring-Closing Metathesis
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account

6
Ma, Ying-Xian; Meng, Zheng; Chen, Chuan-Feng: Synthesis of Substituted Iptycenes
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cluster

31
Cluster Cover Page
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33
Browne, Duncan L.: Cluster Preface: Progress in Organo-Fluorine Chemistry
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36
Xu, Peng; Guo, Shuo; Wang, Liyan; Tang, Pingping: Recent Advances in the Synthesis of Difluoromethylated Arenes
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40
Dai, Xiaoyang; Cahard, Dominique: Regio- and Stereocontrolled Nucleophilic Trifluoromethylthiolation of Morita–Baylis–Hillman Carbonates
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Supporting Information
45
Lishchynskyi, Anton; Mazloomi, Zahra; Grushin, Vladimir V.: Trifluoromethylation and Pentafluoroethylation of Vinylic Halides with Low-Cost RfH-Derived CuRf (Rf = CF3, C2F5)
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Supporting Information
51
Breen, Jessica R.; Sandford, Graham; Patel, Bhairavi; Fray, Jonathan: Synthesis of 4,4-Difluoro-1H-pyrazole Derivatives
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Supporting Information
55
Tarui, Atsushi; Miyata, Erina; Tanaka, Ayumi; Sato, Kazuyuki; Omote, Masaaki; Ando, Akira: Stereoselective Suzuki Coupling Reaction of an α-Bromo-α-fluoro-β-lactam
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Supporting Information
59
Zhang, Zhikun; Feng, Jiajie; Xu, Yan; Zhang, Songnan; Ye, Yuxuan; Li, Tianjiao; Wang, Xi; Chen, Jun; Zhang, Yan; Wang, Jianbo: Synthesis of Trifluoromethylated Cycloheptatrienes from N-Tosylhydrazones: Transition-Metal-Free Büchner Ring Expansion
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Supporting Information
63
Kageshima, Yoshiya; Suzuki, Chiharu; Oshiro, Kojun; Amii, Hideki: Highly Controlled Ring-Opening of Siloxydifluorocyclopropanes: A Versatile Route to Cyclic Fluoroketones
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Supporting Information
67
Liu, Yingle; Yang, Yi; Huang, Yangen; Xu, Xiu-Hua; Qing, Feng-Ling: Regio- and Diastereoselective Vinylogous Mannich Addition of 3-Alkenyl-2-oxindoles to α-Fluoroalkyl Aldimines
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Supporting Information
73
Hendriks, Christine M. M.; Reball, Jens; Bolm, Carsten: Methyl 4-Pentafluorosulfanylphenyl Sulfoximines
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Supporting Information
76
Alazet, Sébastien; Billard, Thierry: Electrophilic Aromatic Trifluoromethylthiolation with the Second Generation of Trifluoromethanesulfenamide
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Supporting Information

letter

79
Patel, Bhaven; Hilton, Stephen T.: A Radical-Mediated Approach to the Total Synthesis of Fluorinated Marinoquinoline A and Related Tricyclic and Tetracyclic Congeners
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Supporting Information
84
Antoniak, Damian; Sakowicz, Arkadiusz; Loska, Rafał; Mąkosza, Mieczysław: Direct Conversion of Aromatic Aldehydes into Benzamides via Oxidation with Potassium Permanganate in Liquid Ammonia
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Supporting Information
87
Sarbu, Laura G.; Hopf, Henning; Grunenberg, Jörg; Birsa, Lucian M.: Reduction of Pseudo-geminal Bis(ethynyl)-Substituted [2.2]Paracyclophanes
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91
Sarmah, Manas M.; Prajapati, Dipak: Ultrasound-Mediated One-Pot Synthesis of 7-Methyl-Substituted Pyrido[4,3-d]pyrimidine Scaffolds by a Catalyst-Free Protocol
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Supporting Information
95
Trillo, Paz; Gómez-Martínez, Melania; Alonso, Diego A.; Baeza, Alejandro: 2-Aminobenzimidazole Organocatalyzed Asymmetric Amination of Cyclic 1,3-Dicarbonyl Compounds
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Supporting Information
101
Teimouri, Mohammad Bagher; Asnaashari, Bita; Moayedi, Maryam; Naderi, Soheila: Diastereoselective One-Pot Synthesis of Succinimides Bearing a Chromone Unit
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Supporting Information
108
Hajibabaei, Khadijeh; Zali-Boeini, Hassan: One-Pot Multicomponent Domino Synthesis of 4-Aminothiazole-2(3H)-thiones
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111
Stockton, Kieran P.; Glover, Stephen A.; Greatrex, Ben W.: Nucleophilic Trapping of Alkoxy-Stabilized Oxyallyl Systems Generated from Inosose 2-O-Mesylates
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Supporting Information
116
Li, Yanru; Zhang, Luyan; Yuan, Haiyan; Liang, Fushun; Zhang, Jingping: Rapid α-Amination of N-Substituted Indoles by Using DBU-Activated N-Haloimides as Nitrogen Sources
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Supporting Information
123
Capitta, Francesca; Frongia, Angelo; Ollivier, Jean; Aitken, David J.; Secci, Francesco; Piras, Pier Paolo; Guillot, Régis: Enantioselective Organocatalyzed Desymmetrization of 3-Substituted Cyclobutanones through Michael Addition to Nitroalkenes
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Supporting Information
127
Qian, Jinlong; Yi, Wenbin; Lv, Meifang; Cai, Chun: A Facile and Mild Approach for Stereoselective Synthesis of α-Fluoro-α,β-unsaturated Esters from α-Fluoro-β-keto Esters via Deacylation
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Supporting Information

spotlight

133
Gao, Kai: Hypophosphorous Acid
135
Mears, Paul R.: 3,3,3-Bromodifluoro-1-propene: The Mild Introduction of CF2