DOI:
10.1055/s-00000083
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We focused in particular on the activation of aldehydes with prolinol or MacMillan-type catalysts. In 2013, Huang and co-workers showed that it was possible to activate aldehydes with amines for α-alkynylation with EBX reagents, but only using unsubstituted pyrrolidine as the catalyst, see: Wang Z, Li X, Huang Y.
Angew. Chem. Int. Ed. 2013;
52: 14219
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