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Synlett 2023; 34(05): 423-428
DOI: 10.1055/a-1928-2562
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Special Edition Thieme Chemistry Journals Awardees 2022

Construction and Characterization of a Diphase Two-Dimensional Halogen-Bonded Organic Framework Based on a Pyrene Derivative

Guanfei Gong
a   The Institute for Advanced Studies, Wuhan University, 299 Bayi Road, Wuhan, Hubei 430072, P. R. of China
,
Fei Xie
b   National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. of China
,
Lu Wang
a   The Institute for Advanced Studies, Wuhan University, 299 Bayi Road, Wuhan, Hubei 430072, P. R. of China
,
Jike Wang
a   The Institute for Advanced Studies, Wuhan University, 299 Bayi Road, Wuhan, Hubei 430072, P. R. of China
,
Shigui Chen  ∗
a   The Institute for Advanced Studies, Wuhan University, 299 Bayi Road, Wuhan, Hubei 430072, P. R. of China
› Author AffiliationsThis work was supported by National Natural Science Foundation of China (21702153 and 21801194) and Wuhan Science and Technology Bureau (whkxjsj009).
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Abstract

Crystalline porous materials have received extensive attention due to their fascinating structures and wide range of applications. We report a novel diphase two-dimensional (2D) halogen-bonded organic framework (XOF-TPP) based on 1,3,6,8-tetra(pyridin-4-yl)pyrene (TPP). XOF-TPP was constructed through [N···I+···N] interactions between the pyridyl groups of TPP and iodonium cations. The formation of XOF-TPP was monitored by X-ray photoelectron spectroscopy, IR spectroscopy, powder X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy, and simulated theoretically. Small-angle X-ray scattering indicated that the XOF-TPP exists as a 2D periodic structure. This diphase 2D halogen-bonded organic framework has promise for practical applications in supramolecular functional materials.

Key words

crystalline porous materials - organic frameworks - tetrapyridinylpyrene - halogen bonding

Supporting Information

    Supporting information for this article is available online at https://doi.org/10.1055/a-1928-2562.
  • Supporting Information


Publication History

Received: 31 May 2022

Accepted after revision: 19 August 2022

Accepted Manuscript online:
19 August 2022

Article published online:
07 October 2022

© 2022. Thieme. All rights reserved

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