Fullerene Allylation

M. Nambo; A. Wakamiya; S. Yamaguchi; K. Itami

doi:10.1055/s-0029-1218417

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Synfacts 2010(1): 0041-0041
DOI: 10.1055/s-0029-1218417

Synthesis of Materials and Unnatural Products

Fullerene Allylation

Contributor(s): Timothy M. Swager, Brett VanVeller
M. Nambo*, A. Wakamiya, S. Yamaguchi, K. Itami*
Nagoya University, Japan

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Publication History

Publication Date:
21 December 2009 (online)

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Significance

A palladium-catalyzed tetraallylation of C₆₀ to give a selectively unsymmetrical addition pattern is reported. Further, a monoallylation catalyst system was also developed.