Iron-Catalyzed Oxidative Esterification of Aldehydes using
Boronic Acids

J. N. Rosa; R. S. Reddy; N. R. Candeias; P. M. S. D. Cal; P. M. P. Gois

doi:10.1055/s-0030-1257899

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Synfacts 2010(9): 1060-1060
DOI: 10.1055/s-0030-1257899

Metal-Mediated Synthesis

Iron-Catalyzed Oxidative Esterification of Aldehydes using Boronic Acids

Contributor(s): Paul Knochel, Andreas J. Wagner
J. N. Rosa, R. S. Reddy, N. R. Candeias, P. M. S. D. Cal, P. M. P. Gois*
Universidade de Lisboa, Portugal

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Publication History

Publication Date:
23 August 2010 (online)

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Significance

In situ prepared NHC-iron complexes (NHC = N-heterocyclic carbene) afford very efficiently benzoates via an aerobic oxidative aromatic esterification of aldehydes with boronic acids.