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Synlett 2011(1): 1-5  
DOI: 10.1055/s-0030-1259093
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© Georg Thieme Verlag Stuttgart ˙ New York

Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes

Sibo Lin, Theodor Agapie*
Division of Chemistry and Chemical Engineering, California Institute of Technology, MC127-72, 1200 E. California Blvd.,Pasadena, CA 91125, USA
Fax: +1(626)3956948; e-Mail: agapie@caltech.edu;
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Publication History

Received 12 October 2010
Publication Date:
16 December 2010 (online)

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Abstract

Nickel catalysts have been developed for a wide range of C-C bond formation reactions. Reaction mechanisms proposed for these transformations generally involve catalytic intermediates based on mononickel species. These reactions are reviewed and the possibility of dinickel species active in C-C cross-coupling chemistry is discussed.

Key words

nickel - cross-coupling - alkyl halides - dinuclear mechanism - metal-arene interactions

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