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Synfacts 2011(3): 0295-0295  
DOI: 10.1055/s-0030-1259494
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Synergistic Catalysis of Chiral Gold Complexes and Chiral Anions

Contributor(s): Hisashi Yamamoto, Zhi Li
K. Aikawa, M. Kojima, K. Mikami*
Tokyo Institute of Technology, Japan
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Publication History

Publication Date:
16 February 2011 (online)

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Significance

This paper describes a new syn­ergistic catalyst system consisting of a chiral ­BIPHEP-gold complex and a chiral anion. The catalyst system is capable of catalyzing the intramolecular hydroalkoxylation of allenes.