Ni-Catalyzed Opening of Styrenyl Epoxides with Boronic Acids

D. K. Nielsen; A. G. Doyle

doi:10.1055/s-0030-1260881

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Synfacts 2011(9): 0996-0996
DOI: 10.1055/s-0030-1260881

Metal-Mediated Synthesis

Ni-Catalyzed Opening of Styrenyl Epoxides with Boronic Acids

Contributor(s): Paul Knochel, Andreas K. Steib
D. K. Nielsen, A. G. Doyle*
Princeton University, USA

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Publication History

Publication Date:
19 August 2011 (online)

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Significance

A new method for opening styrenyl epoxides with various boronic acids, yielding β-substituted alcohol products is described. The reaction is catalyzed by a biarylmonophosphineligated nickel complex.