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Synfacts 2011(10): 1145-1145
DOI: 10.1055/s-0030-1261091
DOI: 10.1055/s-0030-1261091
Polymer-Supported Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Oxidation of Olefins and Alcohols with Pt@Fe2O3 Nanowires
H. Hong, L. Hu, M. Li, J. Zheng, X. Sun, X. Lu, X. Cao*, J. Lu*, H. Gu*
Soochow University and Functional Nano & Soft Materials Laboratory & Jiangsu Key Laboratory for Carbon-Based, Functional Materials and Devices, Suzhou, P. R. of China
Further Information
Publication History
Publication Date:
20 September 2011 (online)
Significance
Iron oxide coated platinum nanowires (Pt@Fe2O3 NWs) 1 bearing a one-dimensional (1D) nanostructure were prepared by the oxygen oxidation of PtFex NWs in oleylamine. The diameter of the PtFex NWs was ca. 1.9 nm, and that of Pt@Fe2O3 NWs 1 increased to be approximately 2.8 nm. Their length was several micrometers. Catalyst 1 was applied to the oxidation of olefins and alcohols to afford the corresponding aldehydes and ketones 2-11 in up to 93% yield.