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Synthesis 2013; 45(19): 2706-2710
DOI: 10.1055/s-0033-1339648
DOI: 10.1055/s-0033-1339648
paper
A Simple and Effective Synthesis of Aryl Azides via Arenediazonium Tosylates
Further Information
Publication History
Received: 22 May 2013
Accepted after revision: 30 July 2013
Publication Date:
14 August 2013 (online)
Abstract
Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH. Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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