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Synthesis 2015; 47(15): 2270-2280
DOI: 10.1055/s-0034-1380657
DOI: 10.1055/s-0034-1380657
paper
Selective Oxidation of 1-Tetralones to 1,2-Naphthoquinones with IBX and to 1,4-Naphthoquinones with Oxone® and 2-Iodobenzoic Acid
Further Information
Publication History
Received: 21 January 2015
Accepted after revision: 26 March 2015
Publication Date:
07 May 2015 (online)
Abstract
The preparation of naphthoquinones by oxidation of 1-tetralone derivatives is reported. 1,2-Naphthoquinones were prepared by oxidation with IBX and 1,4-naphthoquinones were prepared by oxidation using Oxone® and 2-iodobenzoic acid. The mechanistic pathways are also discussed.
Key words
selective oxidation - IBX - 1,2-naphthoquinones - 1,4-naphthoquinones - hypervalent iodine reagentsSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380657.
- Supporting Information
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