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Synthesis 2017; 49(01): 159-166
DOI: 10.1055/s-0035-1562620
DOI: 10.1055/s-0035-1562620
paper
Kinetic Resolution of 5-Substituted Cyclohexenols by Palladium-Catalyzed Asymmetric Redox-Relay Heck Reaction
Further Information
Publication History
Received: 15 July 2016
Accepted: 22 July 2016
Publication Date:
09 September 2016 (online)
This paper is dedicated to Professor Dieter Enders
Abstract
The kinetic resolution of 2-substituted-cyclohexenols via palladium-catalyzed asymmetric redox-relay Heck reaction was realized, providing optically active 2-substituted cyclohexenols and trans-3,5-disubstituted cyclohexan-1-ones in high yield and good enantioselectivities with an S factor up to 22.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1562620.
- Supporting Information
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