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Synthesis 2018; 50(05): 1015-1019
DOI: 10.1055/s-0036-1589153
DOI: 10.1055/s-0036-1589153
psp
Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes
The present project is supported by CREST, JST (CREST-JPMJCR1541). We thank JSPS KAKENHI Grant Numbers JP17H01201 and JP15H05798 in Precisely Designed Catalysts with Customized Scaffolding. A.E. is a recipient of the JSPS Predoctoral Fellowships for Young Scientists.Further Information
Publication History
Received: 02 November 2017
Accepted after revision: 18 November 2017
Publication Date:
14 December 2017 (online)
Abstract
A synthetic method for N-heterocyclic carbene- and phosphine-based PCP-type pincer ligand is described on a large scale. Some transition-metal complexes bearing the PCP-type pincer ligand are prepared and characterized by X-ray crystal structure analysis.
Key words
N-heterocyclic carbene - PCP ligand - phosphine - pincer ligand - transition-metal complexesSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1589153.
- Supporting Information
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