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Synthesis 2018; 50(21): 4283-4289
DOI: 10.1055/s-0037-1610220
DOI: 10.1055/s-0037-1610220
paper
Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives
Financial support was provided by NNSFC (Grant 21672009), MOST (2015CB856600) and RFBR (grant No. 16-53-52030).Further Information
Publication History
Received: 14 June 2018
Accepted after revision: 03 July 2018
Publication Date:
25 July 2018 (online)
Abstract
Unlike the facile addition of aliphatic amines to fullerenes, heteroaromatic compounds with NH group do not react directly with pristine fullerenes. The present work reports the preparation of several cyclopentadienyl type [60]fullerene derivatives with pyrazole and pyrrole addends through replacement reactions of C60Cl6 in the presence of tetrabutylammonium bromide. The method has also been applied for the synthesis of aniline and methoxyamine [60]fullerene cyclopentadienyl type adducts. Radical species were involved in the reaction mechanism.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1610220.
- Supporting Information
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