Transition-Metal-Catalyzed Cross-Coupling Reactions of Grignard Reagents

Abstract

Transition-metal-catalyzed cross-coupling of organo­halides, ethers, sulfides, amines, and alcohols (and derivatives thereof) with Grignard reagents, known as the Kumada–Tamao–Corriu reaction, can be used to prepare important intermediates in the synthesis of numerous­ biologically active compounds. The most frequently used transition metals are nickel, palladium, and iron, but there are several examples for cross-coupling reactions catalyzed by copper, cobalt, manganese, chromium, etc. salts and complexes. The aim of this review is to summarize the most important transition-metal-catalyzed cross-coupling reactions realized in the period 2000 to 2020.

1 Introduction

2 Nickel Catalysis

3 Palladium Catalysis

4 Iron Catalysis

5 Catalysis by Other Transition Metals

5.1 Cobalt Catalysis

5.2 Copper Catalysis

5.3 Manganese Catalysis

5.4 Chromium Catalysis

6 Conclusion

Key words

transition metals - Grignard reagent - cross-coupling - organometallic­ reagent - organic halides - Kumada–Tamao–Corriu coupling­

Publication History

Received: 01 September 2020

Accepted after revision: 19 October 2020

Article published online:
10 December 2020

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