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Synthesis 1990; 1990(9): 799-801
DOI: 10.1055/s-1990-27019
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A Convenient Method for the Synthesis of Substituted 2-Methoxycarbonyl- and 2-Cyano-allylphosphonates. The Allyl Phosphite - Allylphosphonate Rearrangement

Tomasz Janecki* , Ryszard Bodalski
  • *Institute or Organic Chemistry, Technical University, Żwirki 36, PL-90-924 Łódź, Poland
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Publication History

Publication Date:
17 September 2002 (online)

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The thermally induced Arbuzov rearrangement of allyl diethyl phosphites gives, under unprecedented mild conditions, a variety of diethyl allylphosphonates with high stereoselectivity and in high yield.

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