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Synthesis 1990; 1990(12): 1151-1152
DOI: 10.1055/s-1990-27121
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A Convenient Route to Aryl Trifluoromethyl Sulfones by Fluoride-Catalyzed Cross-Coupling of Arenesulfonyl Fluorides with (Trifluoromethyl)trimethylsilane and (Trifluoromethyl)trimethylstannane

A. A. Kolomeitsev* , V. N. Movchun, N. V. Kondratenko, Yu. L. Yagupolski
  • *Institute of Organic Chemistry of the Academy of Sciences of the Ukrainian SSR, SU-252094 Kiev, USSR
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Publication Date:
02 May 2002 (online)

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Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-d by reacting with (trifluoromethyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yields.

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