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Synlett 1992; 1992(6): 521-523
DOI: 10.1055/s-1992-21401
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Domino-Heck Coupling of Aryl Halides and Dicyclopentadiene: A Simple Access to Polycyclic Arene-Anellated Cyclopentadienes as Ligands for Metal Complexes

Karsten Albrecht* , Oliver Reiser, Martin Weber, Armin de Meijere
  • *Institut für Organische Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, D-3400 Göttingen, Germany
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Publication Date:
08 March 2002 (online)

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Domino coupling products of haloarenes and norbornene as well as dicyclopentadiene can be converted to polycyclic aromatic compounds like benzo[e]pyrene (3), benzo[e]cyclopenta[I]pyrene (4), 7-phenyl-1H-cyclopenta[I]phenanthrene (10) and 1H-cyclopenta[f][3,8]phenanthroline (16). Compounds 4 and 10 can serve as new ligands in metal complexes such as ferrocenes 17, 18a and titanocene 18b.

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