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Synlett 1993; 1993(8): 573-574
DOI: 10.1055/s-1993-22533
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Preparation of α-Halo-α,β-Unsaturated Bicyclic Lactams and Their Use in Palladium-Catalyzed Cross Coupling Reactions

Bradley J. Newhouse* , A. I. Meyers, Nilantha S. Sirisoma, Matthew P. Braun, Carl R. Johnson
  • *Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA
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Publication Date:
19 March 2002 (online)

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Efficient syntheses of α-halo-α,β-unsaturated lactams from the corresponding saturated and unsaturated lactams are described. These substrates undergo palladium-catalyzed Stille and Suzuki couplings, furnishing α-substituted-α,β-unsaturated lactams in good yields.

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