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Synlett 1994; 1994(1): 43-45
DOI: 10.1055/s-1994-22732
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Synthetic Studies of Halichondrin B, an Antitumor Polyether Macrolide Isolated from a Marine Sponge. 3. Synthesis of C27-C36 Subunit via Completely Stereoselective C-Glycosylation to the F Ring

K. Horita* , Y. Sakurai, M. Nagasawa, S. Hachiya, O. Yonemitsu
  • *Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060, Japan
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Publication Date:
22 March 2002 (online)

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A stereoselective synthesis of the C27-C36 fragment of halichondrin B starting from L-tartaric acid using an efficient acidcatalyzed C-glycosylation to the F ring as the key step is reported.

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