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Synlett 1994; 1994(3): 179-180
DOI: 10.1055/s-1994-22784
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Synthesis of Alkynylsilanes by Samarium-Mediated Alkylation of Ethynylsilanes

Masahiro Murakami* , Minoru Hayashi, Yoshihiko Ito
  • *Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Kyoto 606-01, Japan
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Publication Date:
22 March 2002 (online)

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Various alkynylsilanes are synthesized by samarium-mediated coupling reactions of ethynylsilanes with haloalkanes including α- and β-branched ones.

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