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Synlett 1994; 1994(3): 189-190
DOI: 10.1055/s-1994-22789
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Rate Enhancement of Palladium-Catalyzed Alkene to Alkenyl and Aryl Halide Couplings under High Pressure

Katharina Voigt* , Ute Schick, Frank E. Meyer, Armin de Meijere
  • *Institut für Organische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, D-37077 Göttingen, Germany
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Publication Date:
22 March 2002 (online)

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Palladium-catalyzed coupling reactions of vinyl- and aryl bromides with styrene proceed at significantly lower temperatures when high pressure (10 kbar) is applied. Even a vinyl chloride could be coupled under 10 kbar.

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