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Synlett 1994; 1994(4): 231-232
DOI: 10.1055/s-1994-22805
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Bryostatins : The Asymmetric Synthesis of the C17-C27 Fragment

J. De Brabander* , M. Vandewalle
  • *University of Gent, Department of Organic Chemistry, Laboratory for Organic Synthesis, Krijgslaan, 281 (S.4), B-9000 GENT (Belgium)
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Publication Date:
22 March 2002 (online)

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Disconnection at C20-C21 leads to two fragments. The C21-C27 fragment is constructed from D-isoburyl lactate via chelationcontrolled allylation. The C17-C20 fragment is obtained from D-pantolactone.

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