Selective Catalytic Transformations of Alkynyl Cyclic Carbonates into either Homopropargylic or α-Allenyl Alcohols

C. Darcel; S. Bartsch; C. Bruneau; P. H. Dixneuf

doi:10.1055/s-1994-22889

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml

Share / Bookmark

Facebook X Linkedin Weibo

Download PDF

Synlett 1994; 1994(6): 457-458
DOI: 10.1055/s-1994-22889

letter

© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Selective Catalytic Transformations of Alkynyl Cyclic Carbonates into either Homopropargylic or α-Allenyl Alcohols

C. Darcel^* , S. Bartsch, C. Bruneau, P. H. Dixneuf

^*Laboratoire de Chimie de Coordination Organique, URA CNRS 415, Campus de Beaulieu, Université de Rennes, F-35042 Rennes, France

Further Information

Publication History

Publication Date:
18 September 2002 (online)

PDF Download Permissions and Reprints All articles of this category

Alkynyl cyclic carbonates 3 are selectively transformed by hydrogenolysis with triethylammonium formate catalyzed by Pd(dba)₂ into homopropargylic alcohols 4 in the presence of PBu₃ or into α-allenyl alcohols 5 with (1.2-diphenylphosphino)ethane or (1,3-diphenylphosphino)propane ligand.

>