Catalytic Isomerization of 1-Siloxy-1-vinylcyclopropanes to 1-Siloxycyclopentenes by Nickel(0)

Ilhyong Ryu; Kiyoshi Ikura; Yukihiro Tamura; Junko Maenaka; Akiya Ogawa; Noboru Sonoda

doi:10.1055/s-1994-23057

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Synlett 1994; 1994(11): 941-942
DOI: 10.1055/s-1994-23057

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Catalytic Isomerization of 1-Siloxy-1-vinylcyclopropanes to 1-Siloxycyclopentenes by Nickel(0)

Ilhyong Ryu^* , Kiyoshi Ikura, Yukihiro Tamura, Junko Maenaka, Akiya Ogawa, Noboru Sonoda

^*Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565, Japan

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Publication Date:
22 March 2002 (online)

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Catalytic isomerization of 1-siloxy-1-vinylcyclopropanes to 1-siloxycyclopentenes was achieved with high efficiency by NiCl₂(PPh₃)₂/Zn under refluxing toluene or xylene.

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