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Synlett 1996; 1996(10): 966-968
DOI: 10.1055/s-1996-5650
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Lipase-Assisted Synthesis of β-Gal-(1→3)-GalNAc

Kwo-Feng Hsiao, Shui-Tein Chen, Kung-Tsung Wang, Shih-Hsiung Wu*
  • *Institute of Biological Chemistry, Academia Sinica, 128, Yan-Chiu-Yuan Road, Sec II, Nankang, Taipei, Taiwan 11529, R.O.C., Tel: 886-2-7855981 ext 7101, Fax: 886-2-7883473
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Publication Date:
31 December 2000 (online)

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Regiospecific ethanolysis of anomeric acetate (1, 2, and 3) and benzoylation on 6-OH (7) by lipase in anhydrous organic solvents will be described. The derivatives are applied to the synthesis of β-Gal-(1→3)-GalNAc.

lipase - regioselective ethanolysis - regioselective benzoylation

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