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Synthesis 2005(14): 2445-2448  
DOI: 10.1055/s-2005-872087
PSP
© Georg Thieme Verlag Stuttgart · New York

Large-Scale Synthesis of Chiral Ferrocenyl Imino-Phosphines

Pierluigi Barbaro*, Claudio Bianchini, Giuliano Giambastiani*
Istituto di Chimica dei Composti Organo Metallici - CNR, Area di Ricerca di Firenze, Via Madonna del Piano, 50019 Sesto Fiorentino-Firenze, Italy
Fax: +39(055)5225203; e-Mail: pierluigi.barbaro@iccom.cnr.it; e-Mail: giuliano.giambastiani@iccom.cnr.it;
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Publication History

Received 15 June 2004
Publication Date:
20 July 2005 (online)

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Abstract

A convenient, multigram-scale synthesis of ferrocenyl imino-phosphine ligands, combining planar and central chirality, and featured by a flexible and easy-to-tune molecular structure has been developed.

Key words

imines - ferrocenes - phosphorus - ligands - stereoselective synthesis

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