Er(OTf)3 as New Efficient Catalyst for the Stereoselective Synthesis of C-Pseudoglycals

Antonio Procopio; Renato Dalpozzo; Antonio De Nino; Monica Nardi; Beatrice Russo; Antonio Tagarelli

doi:10.1055/s-2005-918504

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Synthesis 2006(2): 332-338
DOI: 10.1055/s-2005-918504

PAPER

Er(OTf)₃ as New Efficient Catalyst for the Stereoselective Synthesis of C-Pseudoglycals

Antonio Procopio*^a, Renato Dalpozzo^b, Antonio De Nino^b, Monica Nardi^b, Beatrice Russo^a, Antonio Tagarelli^b
^a Dipartimento Farmaco-Biologico, Università degli Studi della Magna Grascia Complesso Ninì Barbieri, Roccelletta di Borgia (CZ), 88021, Italy
Fax: +39(0961)391270; e-Mail: procopio@unicz.it;
^b Dipartimento di Chimica, Università della Calabria, Ponte Bucci, Arcavacata di Rende (CS), 87030, Italy

Further Information

Publication History

Received 24 June 2005
Publication Date:
21 December 2005 (online)

Abstract
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Abstract

Er(OTf)₃ is a useful catalyst for the Ferrier rearrangement furnishing high yields of products, cleaner reaction profiles, short reaction times, mild reaction conditions, high stereoselectivity and recoverability of the catalyst which is also commercially available.

Key words

C-glycosylation - Lewis catalyst - erbium (III) - triflate

References

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The purity of recovered Er(OTf)₃ was confirmed by comparison with the IR spectrum of commercial product.