A New Method for the Reduction of Secondary Phosphine Oxides

C. A. Busacca; J. C. Lorenz; N. Grinberg; N. Haddad; M. Hrapchak; B. Latli; H. Lee; P. Sabila; A. Saha; M. Sarvestani; S. Shen; R. Varsolona; X. Wei; C. H. Senanayake

doi:10.1055/s-2005-921633

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Synfacts 2005(3): 0335-0335
DOI: 10.1055/s-2005-921633

Metal-Mediated Synthesis

A New Method for the Reduction of Secondary Phosphine Oxides

Contributor(s): Paul Knochel, Andrei Gavryushin
C. A. Busacca*, J. C. Lorenz, N. Grinberg, N. Haddad, M. Hrapchak, B. Latli, H. Lee, P. Sabila, A. Saha, M. Sarvestani, S. Shen, R. Varsolona, X. Wei, C. H. Senanayake
Boeringer-Ingelheim, Inc., Ridgefield, USA

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Publication History

Publication Date:
22 November 2005 (online)

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Significance

Secondary phosphines are extremely important and convenient intermediates in the synthesis of ligands for transition-metal catalysis. This procedure is the best method published so far for the preparation of those compounds from readily available secondary phosphine oxides.