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Synthesis 2006(18): 3080-3084  
DOI: 10.1055/s-2006-950203
PAPER
© Georg Thieme Verlag Stuttgart · New York

AIBN-Initiated Radical Reactions of Ethyl Phosphinate

Monika I. Antczak, Jean-Luc Montchamp*
Department of Chemistry , Texas Christian University, Box 298860, Fort Worth, TX 76129, USA
Fax: +1(817)2575851; e-Mail: j.montchamp@tcu.edu;
Further Information

Publication History

Received 27 February 2006
Publication Date:
21 August 2006 (online)

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Abstract

Ethyl phosphinate adds to alkenes and alkynes under thermal radical conditions with AIBN as the initiator.

Key words

phosphorus - free radical - phosphinates - AIBN - hypophosphite

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