TY - JOUR AU - Liu, Meng-Qi; Zhou, Ai-Hua; Jiang, Shuang; Wang, Jia-Qi; Ye, Long-Wu TI - Highly Diastereoselective Synthesis of Cyclopentenones via a One-Pot Gold Catalysis, Nazarov Cyclization and Alkylation Cascade SN - 0039-7881 SN - 1437-210X PY - 2014 JO - Synthesis JF - Synthesis LA - EN VL - 46 IS - 16 SP - 2161 EP - 2167 ET - 2014/04/09 DA - 2014/08/05 KW - gold catalysis KW - Nazarov cyclization KW - alkylation reaction KW - one-pot cascade KW - Lewis acids AB - Starting from readily available propargylic carboxylates, three sequential transformations [gold-catalyzed tandem reaction, scandium(III) trifluoromethanesulfonate catalyzed Nazarov cyclization, alkylation reaction] in a one-pot process led to the formation of cyclopentenone derivatives in excellent diastereoselectivities and moderate to good overall yields. PB - © Georg Thieme Verlag DO - 10.1055/s-0033-1341204 UR - http://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0033-1341204 ER -