TY - JOUR AU - Maity, Asim; Powers, David C. TI - Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis SN - 0936-5214 SN - 1437-2096 PY - 2019 JO - Synlett JF - Synlett LA - EN VL - 30 IS - 03 SP - 257 EP - 262 ET - 2018/12/11 DA - 2019/01/30 KW - aerobic oxidation KW - hypervalent iodine KW - organocatalysis KW - sustainable synthesis AB - Here, we highlight the recent development of aerobic oxidation catalysis via hypervalent I(III) and I(V) intermediates. The described chemistry intercepts reactive intermediates generated during aldehyde autoxidation to accomplish the oxidation of aryl iodides. The aerobically generated hypervalent iodine intermediates are utilized to couple an array of substrate functionalization chemistry to the reduction of O2.1 Introduction2 Chemistry of Aerobically Generated I(III) Intermediates3 Chemistry of Aerobically Generated I(V) Intermediates4 Conclusions PB - © Georg Thieme Verlag DO - 10.1055/s-0037-1610338 UR - http://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0037-1610338 ER -