TY - JOUR AU - Reinus, Brandon J.; Kerwin, Sean M. TI - N-Alkynyl Pyrrole Based Total Synthesis of Shensongine A SN - 0039-7881 SN - 1437-210X PY - 2019 JO - Synthesis JF - Synthesis LA - EN VL - 51 IS - 21 SP - 4085 EP - 4105 ET - 2019/08/12 DA - 2019/10/16 KW - cross-coupling KW - alkynes KW - nitrogen heterocycles KW - spiroketalization KW - shensongine A KW - pyrrole spiroketal alkaloids KW - total synthesis AB - A copper-catalyzed N-alkynylation of pyrrole and a gold-catalyzed spiroketalization were key steps in the total synthesis of the pyrrole spiroketal alkaloid shensongine A. The preparation of this alkaloid is concise and amenable to the rapid synthesis of a diverse library of compounds. PB - © Georg Thieme Verlag DO - 10.1055/s-0037-1611904 UR - http://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0037-1611904 ER -