TY - JOUR AU - Chen, Tieqiao; Tan, Qihang; Liu, Xue; Liu, Long; Huang, Tianzeng; Han, Li-Biao TI - Phosphorylation of Carboxylic Acids and Their Derivatives with P(O)–H Compounds Forming P(O)–C Bonds SN - 0039-7881 SN - 1437-210X PY - 2020 JO - Synthesis JF - Synthesis LA - EN VL - 53 IS - 01 SP - 95 EP - 106 DA - 2020/09/30 KW - phosphorylation KW - carboxylic acids KW - decarboxylation KW - decarbonylation KW - cross coupling AB - Herein, we highlight advances in the phosphorylation of readily available carboxylic acids and their derivatives forming synthetically important P(O)–sp3C, P(O)–sp2C, and P(O)–spC bonds, with an emphasis on the results demonstrated since 2010. This review examines the challenges associated with the use of this strategy for the synthesis of organophosphorus compounds and details advances in the design of catalytic systems that suppress these problems thus resulting in notable progress. Mechanistic details are discussed where available.1 Introduction2 Formation of P(O)–sp3C Bonds3 Formation of P(O)–sp2C Bonds4 Formation of P(O)–spC Bonds5 Outlook and Conclusion PB - Georg Thieme Verlag KG DO - 10.1055/s-0040-1707286 UR - http://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0040-1707286 ER -