10.20 Phosphorus Analogues of Indolizines
Book
Editors: Diver, S. T.; Donohoe, T. J.; Joule, J. A.
Title: Knowledge Updates 2022/2
Print ISBN: 9783132451933; Online ISBN: 9783132451957; Book DOI: 10.1055/b000000642
1st edition © 2022. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Knowledge Updates
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fuerstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Type: Multivolume Edition
Abstract
This chapter is a complete revision and update of the earlier Science of Synthesis contribution from 2000 describing methods for the synthesis of phosphorus analogues of indolizines. The previous route to this rare ring system, reaction of a phosphole with dimethyl acetylenedicarboxylate, has now been joined by a metathesis-based method leading to the parent dibenzophosphindolizine and its chalcogen derivatives.
Key words
heterocycles - phosphindolizines - phospholes - phosphorus compounds - ring closure - alkene metathesis- 1 Quin LD, Comprehensive Heterocyclic Chemistry II. Katritzky AR, Rees CW, Scriven EFV. Elsevier; Oxford 1996. Vol. 2, p 757.