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Jiang, X. et al.: 2020 Science of Synthesis, 2019/3: Knowledge Updates 2019/3 DOI: 10.1055/sos-SD-114-00088
Knowledge Updates 2019/3

14.9.6 Benzothiopyranones and Benzothiopyranthiones (Update 2019)

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Book

Editors: Jiang, X.; Paquin, J.-F.; Terent'ev, A. ; Wang, M.

Authors: Bityukov, O.; Chen, C.; Dembitsky, V.; Dong, X.; Haufe, G.; Lee, C.-F.; Liu, H.; Terent'ev, A. ; Vil’, V. ; Yu, L.

Title: Knowledge Updates 2019/3

Print ISBN: 9783132429673; Online ISBN: 9783132429703; Book DOI: 10.1055/b-006-166044

1st edition © 2020 Thieme. All rights reserved.
Georg Thieme Verlag, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G.; Nevado Blazquez, C.; Trost, B. M.; You, S.

Type: Multivolume Edition

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Abstract

This chapter is an update to the earlier Science of Synthesis contribution (Section 14.9) describing methods for the synthesis of benzothiopyranones (thiochromenones), benzothiopyranthiones (thiochromenethiones), and related compounds such as 9H-thioxanthen-9-ones and 9H-thioxanthene-9-thiones. General routes to benzothiopyranones involve the intramolecular cyclization of aryl-substituted enones or ynones in the presence of sodium sulfide, and more recent developments with alternative approaches are included herein.

Key words

benzothiopyranones - thiochromenones - thiocoumarins - thiochromenethiones - thioisochromenones - thioisocoumarins - thioisochromenethiones - benzothiopyranthiones - 9H-thioxanthen-9-ones - 9H-thioxanthene-9-thiones - annulation - substituent modification - C-S bond formation
 
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