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Brøndsted Nielsen, M. et al.: 2018 Science of Synthesis, 2018/1: Knowledge Updates 2018/1 DOI: 10.1055/sos-SD-131-00281
Knowledge Updates 2018/1

31.5.1.1.18 Synthesis of Phenols and Phenolates by Substitution (Update 2018)

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Editors: Brøndsted Nielsen, M.; Krause, N.; Rademann, J.; Ramsden, C. A.; Reissig, H.-U.

Authors: Ayad, T.; Bajić, M.; Blanc, A.; González-Bello, C.; Hashmi, A. S. K.; Hessel, V.; Kingston, M.; Pale, P.; Pirat, J.-L.; Pittelkow, M.; Ulfkjaer, A.; Virieux, D.; Volle, J.-N.; Weibel, J.-M.; Žnidaršič-Plazl, P.

Title: Knowledge Updates 2018/1

Print ISBN: 9783132423138; Online ISBN: 9783132423169; Book DOI: 10.1055/b-005-145253

1st edition © 2018 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Koch, G.; Molander, G. A.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

This chapter is an update to the earlier Science of Synthesis review (Section 31.5.1.1) describing the synthesis of monohydric phenols by substitution approaches. It focuses on the literature published in the period 2007–2016, with a particular emphasis on the recent C—H activation methods and hydroxylation by substitution of diverse functional groups, including boronic acids, silanes, and halides.

Key words

phenols - phenolates - hydroxylation - photooxidation - C—H bond activation - metal-catalyzed hydroxylation - arylboronic acids - arylsilanes - alkoxy(aryl)silanes - aryl halides
 
  • 1 Xin H, Koekkoek A, Yang Q, van Santen R, Li C, Hensen EJM. Chem. Commun. (Cambridge) 2009; 7590
  • 10 Seo Y.-K, Yoon JW, Lee JS, Lee U.-H, Hwang YK, Jun C.-H, Horcajada P, Serre C, Chang J.-S. Microporous Mesoporous Mater. 2012; 157: 137
    Search in Google Scholar
  • 20 Zheng Y.-W, Chen B, Ye P, Feng K, Wang W, Meng Q.-Y, Wu L.-Z, Tung C.-H. J. Am. Chem. Soc. 2016; 138: 10080
    Search in Google Scholar
  • 30 Yan Y, Feng P, Zheng Q.-Z, Liang Y.-F, Lu J.-F, Cui Y, Jiao N. Angew. Chem. Int. Ed. 2013; 52: 5827
    Search in Google Scholar
  • 32 Hall DG. Boronic Acids: Preparation and Applications in Organic Synthesis and Medicine. Wiley-VCH; Weinheim, Germany 2007
    Search in Google Scholar
  • 37 Kaboudin B, Abedi Y, Yokomatsu T. Eur. J. Org. Chem. 2011; 6656
  • 38 Chowdhury AD, Mobin SM, Mukherjee S, Bhaduri S, Lahiri GK. Eur. J. Inorg. Chem. 2011; 3232
  • 39 Prakash GKS, Chacko S, Panja C, Thomas TE, Gurung L, Rasul G, Mathew T, Olah GA. Adv. Synth. Catal. 2009; 351: 1567
    Search in Google Scholar
  • 43 Kozytska MV, Dudley GB, In: Comprehensive Heterocyclic Chemistry III Katritzky AR, Ramsden CA, Scriven EFV, Taylor RJK, Elsevier: Oxford UK. 2008; 2. 513-554
    Search in Google Scholar
  • 48 Sergeev AG, Schulz T, Torborg C, Spannenberg A, Neumann H, Beller M. Angew. Chem. Int. Ed. 2009; 48: 7595
    Search in Google Scholar
  • 53 Xu H.-J, Liang Y.-F, Cai Z.-Y, Qi H.-X, Yang C.-Y, Feng Y.-S. J. Org. Chem. 2011; 76: 2296
    Search in Google Scholar