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van Leeuwen, P. W. N. M.: 2014 Science of Synthesis, 2013/7: C-1 Building Blocks in Organic Synthesis 1 DOI: 10.1055/sos-SD-212-00096
C-1 Building Blocks in Organic Synthesis 1

1.1.4 Nonconventional Reaction Media: Hydroformylation, Carbonylation, and Hydroxycarbonylation of Alkenes

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Book

Editor: van Leeuwen, P. W. N. M.

Authors: Ballini, R.; Belderrain, T. R.; Bronger, R. P. J.; Clarke, M. L.; Claver, C.; de Vries, J. G.; Feng, X. M.; Fleischer, I.; Fuentes, J. A.; Godard, C.; Goldfuss, B.; Iwasawa, N.; Kamer, P. C. J.; Lin, L. L.; Liu, X. H.; Mejía, E.; Monflier, E.; Mortreux, A.; Nicasio, M. C.; Perandones, B. F.; Petrini, M.; Sauthier, M.; Takaya, J.; Tauchert, M. E.; Tilloy, S.; Vogt, D.

Title: C-1 Building Blocks in Organic Synthesis 1

Subtitle: Additions to Alkenes, Alkynes, and Carbonyl Compounds

Print ISBN: 9783131707611; Online ISBN: 9783132064416; Book DOI: 10.1055/b-003-125818

2014 © 2014. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: C-1 Building Blocks in Organic Synthesis

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Type: Multivolume Edition

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Abstract

This chapter focuses on catalytic reactions involving the use of carbon monoxide and alkenes together with tertiary substrates such as hydrogen, alcohols, amines, or water where the catalyst recovery and recycling has been emphasized via the use of biphasic media. These atom-economical catalytic reactions result in the synthesis of aldehydes, esters, amines, and carboxylic acids, as well as polyketones, where the activity and regioselectivity concerns have been addressed.

Key words

hydroformylation - hydroesterification - carbonylation - hydroxycarbonylation - carbon monoxide - biphasic catalysis - ionic liquid - water-soluble ligands - phosphines - cyclodextrins - recycling - regioselectivity
 
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