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Muñiz, K.: 2018 Science of Synthesis, 2017/4: Catalytic Oxidation in Organic Synthesis DOI: 10.1055/sos-SD-225-00261
Catalytic Oxidation in Organic Synthesis

7 Gold-Catalyzed Oxidation of Alkynes

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Editor: Muñiz, K.

Authors: Andries-Ulmer, A.; Bellina, F.; Berkessel, A.; Borrell, M.; Caballero, A.; Calleja, P.; Chemler, S. R.; Chen, P.; Costas, M.; Díaz-Requejo, M. M.; Dorel, R.; Dornan, L. M.; Ebner, D. C.; Echavarren, A. M.; Engler, H.; Esguerra, K. V. N.; Farràs, P.; Funes-Ardoiz, I.; Garrido-Barros, P.; Gimbert-Suriñach, C.; Gómez-Arrayas, R.; Griesbeck, A. G.; Gulder, T.; Hughes, N. L.; Ikariya, T.; Ishihara, K.; Jiao, N.; Kayaki, Y.; Kleczka, M.; Leuther, T. M.; Li, Z.; Liu, G.; Llobet, A.; Lumb, J.-P.; Martínez, C.; Maseras, F.; Muldoon, M. J.; Muñiz, K.; Park, N.; Patel, H. H.; Perego, L. A.; Pérez, P. J.; Race, N. J.; Rodríguez, N.; Sigman, M. S.; Sillner, S.; Singh, F. V.; Stoltz, B. M.; Uyanik, M.; Vicens, L.; Wdowik, T.; Wirth, T.; Wright, A. C.

Title: Catalytic Oxidation in Organic Synthesis

Print ISBN: 9783132012318; Online ISBN: 9783132403710; Book DOI: 10.1055/b-003-129345

1st edition © 2018. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

Also available at
 


Abstract

This chapter reviews gold-catalyzed inter- and intramolecular oxidative reactions of alkynes proceeding through α-oxo gold(I) carbenes or related intermediates. Oxidative reactions of enynes and applications of gold-catalyzed oxidative reactions in total synthesis are also covered.

Key words

gold - alkynes - enynes - cyclizations - carbenes - N-oxides - sulfoxides - nitrones
 
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