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Muniz, K.: 2018 Science of Synthesis, 2017/4: Catalytic Oxidation in Organic Synthesis DOI: 10.1055/sos-SD-225-00292
Catalytic Oxidation in Organic Synthesis

8.2 Enantioselective Oxidation of Alcohols

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Book

Editor: Muniz, K.

Authors: Andries-Ulmer, A.; Bellina, F.; Berkessel, A.; Borrell, M.; Caballero, A.; Calleja, P.; Chemler, S.; Chen, P.; Costas, M.; Díaz-Requejo, M. M.; Dorel, R.; Dornan, L.; Ebner, D.; Echavarren, A. M.; Engler, H.; Esguerra, K.; Farràs, P.; Funes, I.; Garrido, P.; Gimbert-Suriñach, C.; Gómez-Arrayas, R.; Griesbeck, A. G. ; Gulder, T.; Hughes, N.; Ikariya, T.; Ishihara, K. ; Jiao, N.; Kayaki, Y. ; Kleczka, M.; Leuther, T.; Li, Z.; Liu, G.; Llobet, A.; Lumb, J.-P.; Martínez, C.; Maseras, F. ; Muldoon, M.; Muniz, K.; Park, N.; Patel, H.; Perego, L.; Pérez, P.; Race, N.; Rodríguez, Nú.; Sigman, M. S.; Sillner, S.; Singh, F. V. ; Stoltz, B. ; Uyanik, M. ; Vicens, L.; Wdowik, T.; Wirth, T.; Wright, A.

Title: Catalytic Oxidation in Organic Synthesis

Print ISBN: 9783132012318; Online ISBN: 9783132403710; Book DOI: 10.1055/b-003-129345

1st edition © 2018. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

Described herein is a review of methods for the enantioselective oxidation of alcohol derivatives to afford enantioenriched alcohols from the corresponding racemates. This review emphasizes recent discoveries in the field, i.e. those that have been reported since 2011. Topics covered include transfer hydrogenation, aerobic metal catalysis, nitroxyl-based radical catalysis, manganese catalysis, and biocatalysis.

Key words

alcohols - carbonyl compounds - oxidation - enantioselectivity - stereoselectivity - kinetic resolution - desymmetrization - transfer hydrogenation - aerobic metal catalysis - nitroxyl-based radical catalysis - manganese catalysis - iridium catalysis - palladium catalysis - ruthenium catalysis - iron catalysis - vanadium catalysis - biocatalysis
 
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