10 Palladium in Photocatalysis
Buch
Herausgeber: König, B.
Titel: Photocatalysis in Organic Synthesis
Print ISBN: 9783132417021; Online ISBN: 9783132417069; Buch-DOI: 10.1055/b-006-161273
1st edition © 2019. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie
Science of Synthesis Reference Libraries
Übergeordnete Publikation
Titel: Science of Synthesis
DOI: 10.1055/b-00000101
Reihenherausgeber: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Typ: Mehrbändiges Werk
Abstract
The concept of photoredox/transition-metal dual catalysis has been validated as a powerful platform for the construction of carbon–carbon and carbon–heteroatom bonds, and it illustrates the power of rational design in catalysis and the strategic use of mechanistic knowledge and manipulation for the development of novel synthetic methods. This chapter describes recent progress in the combination of visible-light photoredox catalysis with palladium catalysis, highlighting this as a valuable synthetic tool in accessing complex molecules in a rapid and modular fashion.
Schlüsselwörter
Keywords: - photocatalysis - palladium - visible light - photoredox - dual catalysis - C–H functionalization - C(sp2)–H arylation - C(sp2)–H acylation - intramolecular alkenation - intramolecular C–H amination - oxidative carbonylation - α-allylation of amines - decarboxylative allylation - acceptorless dehydrogenation-
15 Chiusoli G. P, Catellani M, Costa M, Motti E, Della Caʼ N, Maestri G. Coord. Chem. Rev 2010; 254: 456
-
23 Tredwell M. J, Gulias M, Gaunt Bremeyer N, Johansson C. C. C, Collins B. S. L, Gaunt M. J. Angew. Chem. Int. Ed 2011; 50: 1076
-
44 Boele M. D. K, van Strijdonck G. P. F, de Vries A. H. M, Kamer P. C. J, de Vries J. G, van Leeuwen P. W. N. M. J. Am. Chem. Soc 2002; 124: 1586
-
55 Jordan-Hore J. A, Johansson C. C. C, Gulias M, Beck E. M, Gaunt M. J. J. Am. Chem. Soc 2008; 130: 16184
-
64 Orito K, Horibata A, Nakamura T, Ushito H, Nagasaki H, Yuguchi M, Yamashita S, Tokuda M. J. Am. Chem. Soc 2004; 126: 14342
-
75 Xuan J, Zeng T.-T, Feng Z.-J, Deng Q.-H, Chen J.-R, Lu L.-Q, Xiao W.-J, Alper H. Angew. Chem. Int. Ed 2015; 54: 1625
-
87 Chowdhury A. D, Weding N, Julis J, Franke R, Jackstell R, Beller M. Angew. Chem. Int. Ed 2014; 53: 6477
-
92 Kato S, Saga Y, Kojima M, Fuse H, Matsunaga S, Fukatsu A, Kondo M, Masaoka S, Kanai M. J. Am. Chem. Soc 2017; 139: 2204
-
93 Ragauskas A. J, Beckham G. T, Biddy M. J, Chandra R, Chen F, Davis M. F, Davison B. H, Dixon R. A, Gilna P, Keller M, Langan P, Naskar A. K, Saddler J. N, Tschaplinski T. J, Tuskan G. A, Wyman C. E. Science (Washington, D. C.) 2014; 344: 709
-
95 Rinaldi R, Jastrzebski R, Clough M. T, Ralph J, Kennema M, Bruijnincx P. C. A, Weckhuysen B. M. Angew. Chem. Int. Ed 2016; 55: 8164
-
98 Parsell T. H, Owen B. C, Klein I, Jarrell T. M, Marcum C. L, Haupert L. J, Amundson L. M, Kenttämaa H. I, Ribeiro F, Miller J. T, Abu-Omar M. M. Chem. Sci 2013; 4: 806