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König, B.: 2019 Science of Synthesis, 2018/6: Photocatalysis in Organic Synthesis DOI: 10.1055/sos-SD-229-00364
Photocatalysis in Organic Synthesis

15 Silicates in Photocatalysis

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Book

Editor: König, B.

Authors: Akita, M. ; Albero, J.; Amador, A. G. ; Ashley, M. A.; Brasholz, M. ; Corcé, V.; DiRocco, D. A.; Dix, S.; Ehrnsberger, P.; Fensterbank, L. ; Gaida, F.; García, H.; Ghosh, I. ; Gilmour, R.; Griesbeck, A. G. ; Gutiérrez Bonet, Á.; Hepburn, H. B. ; Hopkinson, M. N. ; Kelly, C. B.; Koike, T. ; Laha, R. ; Lang, S. B.; Leonori, D. ; Lévêque, C.; Li, P.; Lu, L.-Q. ; Matsui, J. K.; Melchiorre, P. ; Molander, G. A. ; Mudd, R. J.; Ollivier, C.; Pandey, G.; Phelan, J.; Reiser, O.; Rey, Y. P.; Rovis, T.; Ruffoni, A.; Scholz, S. O. ; Schultz, D. M.; Skubi, K. L. ; Speckmeier, E.; Thullen, S. M.; Vollmer, M.; Wang, L. ; Wang, M.; Wei, Y.; Xiao, W.-J. ; Yoon, T. P. ; Zeitler, K. ; Zhou, Q.-Q.

Title: Photocatalysis in Organic Synthesis

Print ISBN: 9783132417021; Online ISBN: 9783132417069; Book DOI: 10.1055/b-006-161273

1st edition © 2019 Georg Thieme Verlag KG
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 

Abstract

Bis(catecholato)silicates have emerged as robust alkyl radical sources under photocatalysis. This chapter describes the preparation of various silicates and their utilization under photocatalytic conditions for the formation of C–C and C–O bonds. The last section focuses on the use of silicates in photoredox/nickel dual catalysis.

Key words

Keywords: - photocatalysis - bis(catecholato)silicates - silicates - photoredox/nickel dual catalysis - photooxidation - C–C bond formation - C–O bond formation - alkyl radicals
 
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