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Fernández, E.: 2020 Science of Synthesis, 2019/6: Advances in Organoboron Chemistry towards Organic Synthesis DOI: 10.1055/sos-SD-230-00048
Advances in Organoboron Chemistry towards Organic Synthesis

5 anti Boron Addition to Alkynes

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Book

Editor: Fernández, E.

Authors: Aggarwal, V. K.; Ahmed, E.-A. M. A.; Aiken, S. G.; Bateman, J. M.; Boldrini, C.; Bose, S. K.; Carbó, J. J.; Cho, H. Y.; Clark, T. B.; Fernández, E.; Fu, Y.; Geetharani, K.; Gong, T.-J.; Ito, H.; Kitanosono, T.; Kobayashi, S.; Kubota, K.; Maseras, F.; Ohmiya, H.; Pineschi, M.; Ping, Y.; Sawamura, M.; Wang, J.; Wang, Y.-F.; Wu, C.; Xu, L.; Yoshida, H.; Zhang, F.-L.

Title: Advances in Organoboron Chemistry towards Organic Synthesis

Print ISBN: 9783132429710; Online ISBN: 9783132429758; Book DOI: 10.1055/b-006-164898

1st edition © 2020. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 


Abstract

Boron additions, such as carboboration, silaboration, diboration, or hydroboration of alkynes, offer efficient strategies for the synthesis of alkenylborons, which are versatile synthetic intermediates. Most of the reported reactions occur in syn addition mode. Accordingly, anti-selective boron addition to alkynes is an important challenge in modern organic synthesis. This chapter describes successful examples of anti-selective boron additions.

Key words

anti selectivity - alkynes - vinylboranes - alkenylboranes - carboboration - silaboration - diborylation - hydroboration
 
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