2.10 Radical Chemistry in Flow
Book
Editors: Fensterbank, L.; Ollivier, C.
Title: Free Radicals: Fundamentals and Applications in Organic Synthesis 2
Print ISBN: 9783132435544; Online ISBN: 9783132435551; Book DOI: 10.1055/b000000086
1st edition © 2021. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Type: Multivolume Edition
Abstract
The past two decades have witnessed a rapid growth in flow-based organic synthesis and synthesis involving radical reactions in flow systems is no exception. Flow microreactors have large surface-to-volume ratios that become available by the employment of tiny channels, and this allows radical reactions to occur with efficient heat transfer and diffusion. Flow photomicroreactors with thin, glass-made channels allow for efficient light penetration, which enables highly efficient photo-radical reactions. This chapter highlights recent advances in both thermal and photo-induced radical reactions, which have achieved increased efficiency by using flow reaction systems.
Key words
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